Chapter 23.5, Problem 5P

Complete this table for different amine compounds. Chemical propylamine quaternary ammonium ion methylphenylamine Molecular formula C3H9N C₂H7N C5H13N C4H10N Structural formula (CH3)3N (CH3)2NH CH 3 I (CH₂) 11 | H3C(CH2) 11 -N-(CH₂)11CH3 NHCH3 (CH₂)11 CH3 CH3CH2CH2-NH-CH3 + Classification Tertiary Quaternary Tertiary Secondary

Draw the structure of the product that will be formed when each of the following amines reacts with sodium nitrite and hydrochloric acid, followed by cuprous chloride.   (a) propylamine

Why is methylamine more basic than aniline?

List at least three (3) physical or spectroscopic methods that can be used to differentiate between benzophenone and benzhydrol. Explain how you would differentiate them.

Given the following compounds Which amine is the least basic? Most basic? Which will not react with benzenesulfonyl chloride (C6H5SO2Cl)?

N-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomers

When comparing the structures of aspirin and acetaminophen, why can acetaminophen exist in a liquid state (i.e. childrens drinkable tylenol) and aspirin cannot? Does it have to do with the carboxylic acid? The question says that liquid aspirin cannot be made. Why would that be?

Draw several molecules of methanamide and show the intermolecular hydrogen bonding that account for the amide’s very high boiling point.

Suppose you were given the structural formula of compound B but only the molecular formulas for compound A and the starting bicyclic amine. Given this information, is it possible, working backward, to arrive at an unambiguous structural formula for compound A? for the bicyclic amine?