Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Draw the product formed when each diene and dienophile react in a Diels-Alder reaction.
соон
CH3
a.
b.
C.
čoOCH3
Deconstruct the given Diels–Alder adduct. Draw the reactants (A and B), in any order, that would be needed to produce the Diels–Alder adduct.
Draw the product formed when each diene and dienophile react in a Diels–Alder reaction.
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- 2) Rank the following dienes in order of increasing rate of Diels-Alder reaction with maleic anhydride. You do not need to explain your ranking. H3C. H3CO Diene A Diene B Diene Carrow_forwardRank the following dienes in their rate of reaction with the same dienophile in a Diels-Alder reaction. For example, 1 = fastest or most reactive diene, 4 = slowest or least reactive diene.arrow_forwardDraw the diene and dienophile that are needed to prepare the following Diels-Alder product. Diene: draw structure. Dienophile: draw structure ..arrow_forward
- 8) Predict the two products that form in following Diels-Alder reaction. Circle the major product. CH₂O H O₂N CH₂OCH3 Harrow_forwardWhat diene and dienophile are needed to prepare each Diels–Alder product?arrow_forwardConsider the four trienes E–H.a.Rank compounds E–H in order of increasing heat of hydrogenation. b.Which compound is most reactive in the Diels–Alder reaction? c. Which compound(s) are unreactive in the Diels–Alder reaction? d.Which compound absorbs the longest wavelength of ultraviolet light?arrow_forward
- Diels Alder does the product is correct? CH2CH3 product CHECH3 H3 C HLC CHECH3arrow_forward10. The following compound was produced in a Diels-Alder reaction. COOH a) How many sp³ hybridized carbons are in this molecule? b) Is this molecule chiral? c) Are the carboxylic acid substituents electron donating group or electron withdrawing group? d) Draw the diene and dienophile which would react together to give this product.arrow_forwardWhich diene is more reactive in a Diels–Alder reaction? CH2=CHCH=CHOCH3 or CH2=CHCH=CHCH2OCH3arrow_forward
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