Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Anacin is an over-the-counter pain reliever that contains aspirin and caffeine. Answer the following questions about each compound.
a.What is the molecular formula?
b. How many lone pairs are present on heteroatoms?
c. Label the hybridization state of each carbon.
d. Draw three additional resonance structures.
a. What is the molecular shape around the labeled carbon atom?b. What is the hybridization around that same carbon?c. Based on this structure, would you expect this molecule to absorb light in the visible spectrum? Why or why not?
Use the ball-and-stick model of vitamin Bg to answer each question.
vitamin Be
a. Draw a skeletal structure of vitamin Bộ.
b. How many sp? hybridized carbons are present?
c. What is the hybridization of the N atom in the ring?
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- Answer the following questions about octocrylene, a common sunscreen component. a. What is the hybridization of each C atom? b. How many lone pairs does octocrylene contain? c. What is the geometry around each C atom? d. Draw two additional resonance structures. e. Label all polar bonds.arrow_forwardAnswer each question about L-dopa, a drug used since 1967 to treat Parkinson's disease. a.Convert the skeletal structure to a Lewis structure. b What is the hybridization and geometry around each labeled atom? c. Label three polar bonds.arrow_forward5. Answer the following questions about the molecules CH2S (C is the centralatom).a. Draw the Lewis structure.b. Write the valence shell electron configuration for C.c. Draw the valence orbital diagram for C.d. Draw the hybridized orbital diagram for C.e. Give a bond description for each bond in the molecule.arrow_forward
- . Draw the Lewis diagram for acetamide. ( CH3CONH2) a. What is the electron geometry around each of the two carbon atoms. b. What is the hybridization type of each of the carbon atoms. c. What are the bond types and orbitals involved in bonding for all bonds between the C and O atoms.arrow_forwardDraw an orbital picture of propene. The bond between and is formed by the overlap of which types of orbitals? a. sp2 and sp2 b. sp3 and sp3 c. sp2 on Ca and sp3 on Cb d. sp3 on Ca and sp2 on Cb The double bond between and is formed by what? a. two sigma bonds b. two pi bonds c. overlap of a p orbital on Cb with a sp2 orbital on Cc. d. overlap of two p orbitals plus overlap of two sp2 orbitalsarrow_forwardWhich can be used as a basis for identifying the type of orbital hybridization of a carbon atom given the Kekule or Lewis structure of the compound? Identify all that apply. Defend your answers. a. number of C atoms around carbon b. number of H atoms around carbon c. number of groups attached to the C atom d. number of lone electron pairs or unpaired electrons around the C atom e. type of bond (single, double, or triple) between C and other atoms around itarrow_forward
- The arrow in the structure points to a bond that is formed by a. overlap between s and sp2 orbitals b. overlap between two sp orbitals c. overlap between two sp3 orbitals d. overlap between sp and sp2 orbitals e. overlap between sp2 and sp3 orbitalsarrow_forwardIndicate the number of sp3-hybridized carbon atoms. Select one: a. 4 b. 6 c. 2 d. 8arrow_forwardWhich hybridized orbital of the carbon interact with the s orbital of the hydrogen to form the highlighted bond? A. 2sp atomic orbitals (Orbital atom 2sp) B. 2sp2 atomic orbitals (Orbital atom 2sp2) C. 2p atomic orbitals (Orbital atom 2p) D. 2sp3 atomic orbitals (Orbital atom 2sp3)arrow_forward
- Carbon dioxide has oxygen atoms that each have two sets of two non-bonded electrons. What type of orbital are these electrons located in? a. sigma bonds, non-hybridized b. pi bonds, hybridized c. sigma bonds, hybridized d. pi bonds, non-hybridizedarrow_forwardCapsaicin is an active component of chili peppers, which are plants belonging to the genus Capsicum. Predict the geometry around each indicated atom. b. Give the orbital hybridization around each indicated atom. Predict the polarity around each indicated atom. а. C. HO capsaicin (spicy component of hot peppers)arrow_forwardAnswer the following questions about amoxicillin, an antibiotic from the penicillin family. NH2 H N. N. НО Но amoxicillin a. Predict the hybridization and geometry around each highlighted atom. b. Label five polar bonds using the symbols &+ and 8–. C. How many n bonds does amoxicillin have? Label them. d. Find a C- H bond containing a carbon atom having a hybrid orbital with 33% s-character.arrow_forward
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