Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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(a) Describe the molecular geometry expected for 1,2,3-butatriene (H2C=C=C=CH2). (b) Two stereoisomers are expected for 2,3,4-hexatriene (CH3CH=C=C=CHCH3). What should be the relationship between these two stereoisomers?
Draw the structure of an alkane with molecular
formula C7H16 that contains (a) one 4° carbon; (b)
only 1° and 2° carbons; (c) 1°, 2°, and 3° hydrogens.
2,3-Dibromoprop-1-ene (C3H4Br2) has four H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to
yield a molecule with the formula C3H3Br,Cl. (a) Identify two H atoms where this substitution would yield constitutional
isomers of C3H3Br,CI; (b) enantiomers of C3H3Br,Cl; (c) diastereomers of C3H3Br,Cl.
H
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H
Br
Br
2,3-Dibromoprop-1-ene
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- A hydrocarbon C5H12 gives only one mono-chlorination product. Identify the hydrocarbon.arrow_forwardName the following hydrocarbons: H (a) H2C=C=C-CH,-CH,-CH3 нн (b) H2C=C-C=C-C=CH2 нн CH3 (c) Н.С—С-СH —CH,—CH—CH, (d) CH;-CH2-C=C-CH2-CH;arrow_forwardArrange the following compounds in increasing order of their property as indicated :(i) CH3COCH3, C6H5COCH3, CH3CHO(reactivity towards nucleophilic addition reaction)(ii) Cl—CH2—COOH, F—CH2—COOH, CH3—COOH (acidic character)arrow_forward
- Compounds A and B are isomers of the molecular formula CyH19Br. Both yield the same alkene Cin an elimination reaction. Hydrogenation of C yields the product 2,3,3,4 tetramethyl pentane. What are the structures of A, B, and C?arrow_forwardsketch the various conformational isomers of 1,3-dimethylcyclohexane. Indicate the position (axial/equatorial) of each of the methyl groups in each structure.arrow_forwardWrite a conformational structure for 1,2,3-trimethylcyclohexane in which all the methyl groups are axial and then show its more stable conformation.arrow_forward
- (a) Chromic acid oxidation of 4-tert-butyl-1,2-dimethylbenzene yielded a single compound having the molecular formula C12H14O4. What was this compound?(b) What product is expected from chromic acid oxidation of 2,3-dihydroindene?arrow_forward5. (a) F H₂CH₂C (b) H ) Draw the three-dimensional structures for the following compounds. H CH3 & H3C NH₂ Br OH H CH3 Brarrow_forwardDraw and name the six isomeric cyclopentane of molecular formula C7H14. These will include four constitutional isomers, of which two show geometric (cis-trans) stereoisomerism.arrow_forward
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