EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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I need help with the mechanisms on these two
reactions please :)
NaOH
A
?
b.
1. Draw a complete arrow pushing mechanism for the following reactions
H₂NNH₂
KOH, A
?
4. Draw a mechanism for the reaction below.
CH3NH2
Synthesize the following compound from cyclohexanol using any other organic or inorganic compounds.
HO.
Part 1 out of 2
Preparation of the Grignard reagent:
Book
rint
rences
OH
draw structure ...
draw structure...
Draw the intermediate product formed above and select the correct reagent A.
O MgBr, O
CH;Br O
Brz
PB13
Draw the intermediate product formed above and select the correct reagent B.
O MgBr O Mgo O
O Mgl, O Mg
Hint
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- Consider the following nucleophilc substitution. LOCH3 Br OCH3 в A a. Identify the reaction conditions A and specify the reaction mechanism for the nucleophilic substitution. Explain your choice. b. Explain why the transformation does not give rise to significant elimination. c. Which product(s) B is formed in the reaction? Please specify the stereochemistry clearly with reference to the reaction mechanism.arrow_forward1. Reactions. Ch0ose 5. Identify (draw the structure showing stereochemistry when required) the major product required to complete the following transformations. NaOH A NaOH B NaOH 2 H (note the 2 equivalents of the aldehyde) D 1.NaOEt 2. H,0* 1.NaOEt 2. H,0* Farrow_forwardSynthesize the following compound from cyclohexanol, ethanol, and any other needed reagents. 2 Part 1 out of 3 Preparation of the Grignard reagent: ok nt nces A OH draw structure ... draw structure ... Draw the intermediate product formed above and select the correct reagent for A. O MgBr, O HBr O NaBr O Br2 Draw the Grignard reagent formed above and select the correct reagent for B. O Mgo O MgBr O MgI, O Mg Hint Solution e to search K.arrow_forward
- a. Propose a stepwise mechanism that accounts for the transformations below. 1. NaOEt/ELOH 2. H,O+, heat OEtarrow_forward3. Show a mechanism for the following reaction. Q.XX NO₂ NO₂arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts, methanal (H CO) or COM. 1. O3 2. H2O2 Drawingarrow_forward
- Draw the major product of this reaction. Ignore inorganic byproducts. 1. Hg(OAc)2, H₂O 2. NaBH4, NaOH Drawing atarrow_forward2a. Draw the mechanism and major product of the synthesis reaction below. b. Give the reagent(s) necessary to synthesize the minor products. Br NaOEt E1arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts and the alkoxide side product. N. H 1. excess LIAIH4 2. H2O Select to Draw w 近arrow_forward
- 5. Predict the major product for each of the following reactions. Include stereochemistry when appropriate. Draw the mechanism for each reaction. a. b. C. d. e. Br CI OH CI H₂O NH3 OTS NaCN MeCN KOPh acetonearrow_forward6. The synthesis of alpha enol derivatives is important since these compounds with appropriate substituents in the correct positions can have desired biological effects, which is why the study of obtaining these compounds is important. Thus, a reaction from alpha-ketones with a lithium derivative is studied. a. Indicate the reaction intermediate and product. b. Perform the reaction mechanism. Eter H20 Intermediate Productarrow_forwarda. Show the major product for the reaction shown and a mechanism for its formation. Do not use any termination steps in your mechansim .. only propogation steps. Br2 hv b. If sufficient bromine is added and the reaction is allowed to proceed further, another product will form from the first. Show a mechanism for the reaction of the product from part a. to form the final product with two bromines attached.arrow_forward
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