CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Textbook Question
Chapter 1, Problem 58E
Write conversion factors (as ratios) for the number of:
- kilometers in 1 mile
- liters in 1 cubic foot
- grams in 1 ounce
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Examine the reaction below. Highlight all bonds that have broken in the reactant.
Br H
H₂C-C-
-H
5
H-C-H
H-C-H
BIE
们
OH
H H
H₂C-C=
H-C-H
H-C-H
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH2=CH₂
CH2=C-CH2-OH + Br₂
Br-CH2-C
-CH₂-OH
Br
CH,CH3
CH3-C-CH-CH2-CH3
он
° CH₂
HO
C-C-CH3 + NH3
CH₂
он
CH3-CH-O-CH3
O-CH3
CH3-C-CH3 + H₂O
O-CH3
CH3CH₂
H
+ H₂O
CH3-C=C-CH2-CH3
• CHI
Δ
Å CH
CH3
H+
CH3
C-H + HO-CH3
H"
Q-CH₂
CH3-C-CH3 + HO-CH3
OH
O substitution
O elimination
addition
substitution
O elimination
addition
O substitution
elimination
addition
O substitution
O elimination
addition
substitution
O elimination
00
addition
Search 5:45 PM Sun Dec 15
Quiz 9
...
ล 25%0
A
Done
Quiz #9 =
Name:
Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
E
HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
Ꭰ
KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
G
H
HBr
Br2
J
CH2N2
➤
K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Chapter 1 Solutions
CHEMISTRY
Ch. 1 - Explain how you could experimentally determine...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - According to one theory, the pressure of a gas...Ch. 1 - The amount of heat required to melt 2 lbs of ice...Ch. 1 - Why do we use an objects mass, rather than its...Ch. 1 - What properties distinguish solids from liquids?...Ch. 1 - How does a heterogeneous mixture differ from a...
Ch. 1 - How does a homogeneous mixture differ from a pure...Ch. 1 - How does an element differ from a compound? How...Ch. 1 - How do molecules of elements and molecules of...Ch. 1 - How does an atom differ from a molecule? In what...Ch. 1 - Many of the items you purchase are mixtures of...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - A sulfur atom and a sulfur molecule are not...Ch. 1 - How are the molecules in oxygen gas, the molecules...Ch. 1 - We refer to astronauts in space as weightless, but...Ch. 1 - As we drive an automobile, we don’t think about...Ch. 1 - Matter is everywhere around us. Make a list by...Ch. 1 - When elemental iron corrodes it combines with...Ch. 1 - As stated in the text, convincing examples that...Ch. 1 - Yeast converts glucose to ethanol and carbon...Ch. 1 - Classify the six underlined properties in the...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - The volume of a sample of oxygen gas changed from...Ch. 1 - A 2.0-mer volume of hydrogen gas combined with 1.0...Ch. 1 - Explain the difference between extensive...Ch. 1 - Identify the following properties as either...Ch. 1 - The density (d) of a substance is an intensive...Ch. 1 - Is one liter about an ounce, a pint, a quart, or a...Ch. 1 - Is a meter about an inch, a foot, a yard, or a...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Give the name and symbol of the prefixes used with...Ch. 1 - Give the name of the prefix and the quantity...Ch. 1 - A large piece of jewelry has a mass of 132.6 g. A...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Express each of the following numbers in...Ch. 1 - Express each of the following numbers in...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - How many significant figures are contained in each...Ch. 1 - How many significant figures are contained in each...Ch. 1 - The following quantities were reported on the...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Consider the results of the archery contest shown...Ch. 1 - Classify the following sets of measurements as...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - The label on a soft drink boule gives the volume...Ch. 1 - The label on a box of cereal gives the mass of...Ch. 1 - Soccer is played with a round ball having a...Ch. 1 - A woman’s basketball has a circumference between...Ch. 1 - How many milliliters of a soft drink are contained...Ch. 1 - A barrel of oil is exactly 42 gal. How many liters...Ch. 1 - The diameter of a red blood cell is about 3104 in....Ch. 1 - The distance between the centers of the two oxygen...Ch. 1 - Is a 197-lb weight lifter light enough to compete...Ch. 1 - A very good 197-Ib weight lifter lifted 192 kg in...Ch. 1 - Many medical laboratory tests are run using 5.0 L...Ch. 1 - If an aspirin tablet Contains 325 mg aspirin, how...Ch. 1 - Use scientific (exponential) notation to express...Ch. 1 - Complete the following conversions between SI...Ch. 1 - Gasoline is sold by the liter in many countries....Ch. 1 - Milk is sold by the liter in many Countries. What...Ch. 1 - A long ton is defined as exactly 2240 lb. What is...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - The gas tank of a certain luxury automobile holds...Ch. 1 - As an instructor is preparing for an experiment,...Ch. 1 - To prepare for a laboratory period, a student lab...Ch. 1 - A chemistry student is 159 cm tall and weighs 45.8...Ch. 1 - In a recent Grand Prix, the winner completed the...Ch. 1 - Solve these problems about lumber dimensions. To...Ch. 1 - The mercury content of a stream was believed to be...Ch. 1 - Calculate the density of aluminum if 27.6 cm3 has...Ch. 1 - Osmium is one of the densest elements known. What...Ch. 1 - Calculate these masses. What is the mass of 6.00...Ch. 1 - Calculate these masses. What is the mass of 4.00...Ch. 1 - Calculate these volumes. What is the volume of 25...Ch. 1 - Calculate these volumes. What is the volume of...Ch. 1 - Convert the boiling temperature of gold, 2966 C,...Ch. 1 - Convert the temperature of scalding water, 54 C,...Ch. 1 - Convert the temperature of the coldest area in a...Ch. 1 - Convert the temperature of dry ice, 77 C, into...Ch. 1 - Convert the boiling temperature of liquid ammonia....Ch. 1 - The label on a pressurized can of spray...Ch. 1 - The weather in Europe was unusually warm during...
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- Select the stronger base: H-CEN equally basic H H H H-C-N H Select the stronger acid: Select the stronger base: Select the stronger base: H -H equally acidic о equally basic NH equally basic оarrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3 CH3 CH3-CH-CH2-C-CH3 + Br₂ CH3 CH3 CH3 CH3-C-CH2-C-CH3 + HBr substitution ○ elimination Br CH3 CHI CHO CHA HO CH он Cl CH3-CH2-CH-CH2-CH3 CH₂ DBU H* - CHI CHO CH3 + H2O Ӧ CH3 CH3-CH2-CH=CH-CH3 + HCI OH Pd/C CH3 CH3-CH-CH2-C-CH3 CH3 H C-CH2-CH3 + HO-CH3 addition substitution elimination ○ addition ○ substitution ○ elimination O addition substitution O elimination addition substitution O elimination addition CH3 C-CH3 + H2 CH3 CH3-O-CH-CH2-CH3 Онarrow_forward=> (8 pts) Use retrosynthetic analysis (that is, use retrosynthetic arrows as was done in class) to suggest a synthesis route for the transformation shown below. Sear bonsarrow_forward
- d) 1. Complete the following reactions; all reactions are at room temperature. No heat is involved here. Show Major product only. Indicate the type of mechanism: SN1 or SN2. (1 pt each) a) Br + b) Br e) OH CH3DH + H20 он HCJ Zn Cl₂ OH + HCI 20 C12 + H-Brarrow_forwardWhat is the IUPAC name for the compound shown? LOH IUPAC name: BIU X2 x²arrow_forwardDon't used Ai solutionarrow_forward
- 2. Write the IUPAC name of the major product that would be obtained from the dehydration of 3,5-dimethylcyclohexanol. What is the type mechanism of the reaction (E1, E2, SN1, SN2)? Draw the detailed mechanism of the reaction. (2.5 pts) 3. In Experiment 8, You synthesized n-butyl bromide using sodium bromide, sulfuric acid and butyl alcohol. (2.5 pts) a. Write the detailed mechanism of this reaction indicating what type of mechanism is this reaction. b. What will happen to the rate of the reaction if NaCl was used instead of NaBr? c. What will be the mechanism of the reaction if t-butyl alcohol is used with NaBr in presence of sulfuric acid? Draw detailed mechanism.arrow_forwardIn each row of the table below, select the stronger acid or base, as instructed. The most acidic H atom in each acid has been highlighted. Select the stronger acid: Select the stronger acid: Select the stronger base: Select the stronger base: H H Tx NH equally acidic equally acidic H equally basic equally basicarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
- Use the information in the pk, table below to determine which side of the equilibrium is favored for each of the reactions in the second table. acid pk, acid PK CHA CHÍNH, 36 CH₂SH OH 9 50 45 CH2=CH2 19 15.9 CH₂OH 15.7 10.3 .OH 10.0 4.8 он OH CH₂OH₂ -2.2 -7.2 снон, + i + OH + CH4 Equilibrium Equation CH₂OH + io OH CH3NH + CH2=CH2 CH3NH₂ + он + + H₁₂-C CH2=CH 0 O Left Favored Equal Right Favored о 0 0arrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. Br K* -OC(CH₁) + Cl₂ + HCI + C½₂ + NH3 + HBr + HOT H₂N + HO H HO substitution O elimination addition substitution ○ elimination addition substitution elimination addition O substitution O elimination O addition 000 substitution O elimination additionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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