Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Why is the H–N–H angle in NH3 smaller than the H–C–H bond angle in CH4? Why is the H–N–H angle in NH4 + identical to the H–C–H bond angle in CH4?
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- Ketene, C2H2O, is a reactant for synthesizing cellulose acetate, which is used to make films, fibers, and fashionable clothing. (a) Write the Lewis structure of ketene. Ketene does not contain an OH bond. (b) Identify the electron-region geometry and the molecular geometry around each carbon atom and all the bond angles in the molecule. (c) Identify the hybridization of each carbon and oxygen atom. (d) Is the molecule polar or nonpolar? Use appropriate data to support your answer.arrow_forwardIdentify the orbitals on each of the atoms that form the bonds in H3CCN. How many bonds and bonds form?arrow_forwardConsider the following molecules: SiH4, PH3, H2S. In each case, a central atom is surrounded by four electron pairs. In which of these molecules would you expect the bond angle to be less than 109.5? Explain your reasoning.arrow_forward
- Formamide, HC(O)NH2, is prepared at high pressures from carbon monoxide and ammonia, and serves as an industrial solvent (the parentheses around the O indicate that it is bonded only to the carbon atom and that the carbon atom is also bonded to the H and the N atoms). Two resonance forms (one with formal charges) can be written for formamide. Write both resonance structures, and predict the bond angles about the carbon and nitrogen atoms for each resonance form. Are they the same? Describe how the experimental determination of the HNH bond angle could be used to indicate which resonance form is more important.arrow_forwardTrue or false The F – N – F bond angle in NF3 is smaller than the H – N – H bond angle in NH3.arrow_forwardIn the following molecule, what is the C-C=C bond angle for carbon A and the H-C=C bond angle for carbon A?arrow_forward
- In the following molecule, what is the H-C-C bond angle for carbon b and what is the O=C-O bond angle for carbon c?arrow_forwardAcrylamide, H2 C=CHC(=0)NH2 , is a known neurotoxin and possible carcinogen. It was a shock to all consumers of potato chips and french fries a few years ago when it was found to occur in those products. H C -N -H C H a Identify all bond angles. O The bond angles around N are approximately 120°. All other angles are 109°. O The bond angles around N are approximately 90°. All other angles are 120°. O The bond angles around N are approximately 109°. All other angles are also 109°. O The bond angles around N are approximately 120°. All other angles are also 120°.arrow_forwardWhat are the angles a and b in the actual molecule of which this is a Lewis structure? H H C H a H C ^ b C a = 11° b=0° H -H Note for advanced students: give the ideal angles, and don't worry about small differences from the ideal that might be caused by the fact that different electron groups may have slightly different sizes. X 3arrow_forward
- What is the FE–S– O bond angle in SOF4?arrow_forwardWhich of the following has the smallest ideal bond angle? CHO2 HCN PF3 H2S O All have the same bond anglearrow_forwardWhich of the following is false. the bond angle in water is smaller than in ammonia because the atomic radius of oxygen is bigger than the one of nitrogen. the bond angle in water is smaller than in ammonia because the O-H bond is shorter than the N-H bond. the bond angle in water is smaller than in ammonia because of the bigger number of lone pairs on the central atom.arrow_forward
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