Answered: Why is rotation about the bond axis…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Why is rotation about the bond axis possible for single-bonded atoms but not double-bonded atoms?

Expert Solution

Step 1

A single bond is a sigma bond.
A double bond is a one sigma bond and one pi bond.
A triple bond is one sigma bond and two pi bond

Geometric isomers:

Geometric isomers are isomer which arises due to different arrangement of atoms or groups around a bond which has restricted rotation. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in the same side of the molecule then it is called cis isomers.
If the two atoms locked in the opposite side of the molecule then it is called trans-isomers.

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