
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Why d7,d8,d9 complexes prefer square planar with pi acceptor strong field ligands
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- Isn't An electron-rich transition metal has a low oxidation state, meaning that the metal centre has gained electrons from the nitrogen on NO when it coordinates as a ligand? Therefore, N-O bond length decases.arrow_forward80 70 60 50 T 40 30 20 10 ATE 10 20 30 40 50 A/B O 1 and 4 2 and 2 O 3 and 3 2 and 3 3 and 4 E/Barrow_forwardIdentify complexes that can have low and high spin configurations and rationalize why they adopt a particular configuration using a strong field / weak field ligand argument based on the spectrochemical series.arrow_forward
- What electronic feature must a donor atom of a ligand have?arrow_forwardAccording to the theory of molecular orbitals, how are ligands classified and what effect do they have on the value of the octahedral field?arrow_forwardMatch the orbitals below to the higher and lower energy levels when an octahedral complex undergoes ligand field splitting. dx2-y2 Orbital 1 Orbital 1 Orbital 2 Orbital 3 Orbital 4 Orbital 5 L d₂2 Orbital 2 L dyz Orbital 3 dxz Orbital 4 [Choose] ◊ [Choose] ↑ [Choose] ◊ [Choose] [Choose] ↑ L dxy Orbital 5arrow_forward
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