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- Draw the structure of each type of compound. a. a D-aldotriose b. an L-ketohexose c. a four-carbon aldonic acid1. Classify the molecule shown according to the location of its carbonyl group and the number of carbon atoms. CH₂OH C=O PIL a. Aldotriose b. Aldotetrose Aldopentose d., Ketotriose Ketotetrose HO-C-H L CH₂OHDraw the products formed when β-D-galactose is treated with each reagent. a. Ag2O + CH3I b. NaH + C6H5CH2Cl c. The product in (b), then H3O+ d. Ac2O + pyridine e. C6H5COCl + pyridine f. The product in (c), then C6H5COCl + pyridine
- Draw the products formed when ß-D-galactose is treated with each reagent.a. Ag2O + CH3Ib. NaH + C6H5CH2Clc. The product in (b), then H3O+d. Ac2O + pyridinee. C6H5COCl + pyridinef. The product in (c), then C6H5COCl + pyridineBe sure to answer all parts. The Fischer projection of D-glucose is shown below. Draw its mirror image as a Fischer projection. CHO OH HO H. draw structure... H. OH H. OH CH,OHstructure of each type of compound. A. D –aldotriose B. L-ketohexose
- Which Fischer projection corresponds to D-glucose? CHO CHO H- -OH но- -H HO H. H- H- -ОН Но H- -ОН но- ČH2OH ČH2OH CH2OH CHO но Но Но H- HO- H- HO- H- -ОН H- OH ČH2OH ČH2OHDraw the products formed when CH3CH2CH2CH2OTs is treated with each reagent.a. CH3SHb. NaOCH2CH3c. NaOHd. KOC(CH3)3Identify the monosaccharides. A. CH₂OH он OH OH O OH OH OH CH₂OH OH B-D-glucose OH B. D. OH OH ОН OH OH Ону OH OH
- a. How many stereocenters are present in this monosaccharide? CH,OH C=0 но H- O- H- HO- ČH2OH b. How many stereoisomers are possible for this monosaccharide? CHO H- HO- H- H- CH2OH10. Draw the reaction of Galactose with Benedict solution. Answer the following questions based on these structures. Here is the terminology you can use to describe the relationships. Structural isomers, Enantiomers, Diastereomers, and no relationship. CHO CHO -H H- Н- CHO HO-H OH H- НО- Н- Н- OH OH CH₂OH CHO H H -ОН -ОН но- Н- CH₂OH H -ОН CH2OH 2 Н- Н- но- НО- CHO -ОН -ОН -H -H CH2OH 8 НО Н- H- НО- -ОН -Н CH₂OH 3 CH₂OH 7 11. What is the relationship between 1 and 4? 12. What is the relationship between 1 and 3? 13. What is the relationship between 1 and 5? 14. What is the relationship between 2 and 9? Н- но 15. What is the relationship between 4 and 10? 16. What is the relationship between 5 and 6? ОН 17. What is the relationship between 2 and 10? CH2OH -ОН -Н CH2OH 9 НО- Н- Н- CH2OH :0 -H OH OH CH2OH 4 НО- НО- Н- H- но- но- CH2OH H——OH -Н -Н CH₂OH 10 H H OH OH CH₂OH 5 Н- но- но- Н- CHO -OH -H H -OH CH2OH 6Draw Haworth projection formulas for the a-anomer of monosaccharides with each of the following Fischer projection formulas. a. CHO HOH H- HO- H -ОН -Η OH CH₂OH b. CHO H -OH H -ОН HO H CH₂OH