Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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### Question 14
**Which shows the correct curved arrows for the mechanism to convert the starting materials to the product?**

#### Answer Choices:
1. (a)
2. (b)
3. (c)
4. (d)

#### Detailed Explanation of Diagrams:

Each of the diagrams (a), (b), (c), and (d) represent different proposed mechanisms for converting the starting material to the product. In each mechanism, curved arrows indicate the flow of electrons during the reaction.

**Diagram (a):**
- The mechanism shows an initial curved arrow from the lone pair on the hydroxyl oxygen (O) to the proton (H) in an adjacent carbon-carbon double bond (C=C).
- Another curved arrow from the carbon-carbon double bond (C=C) to the nitrogen (N) indicates electron flow toward the nitrogen.
- A final arrow from the nitrogen to an adjacent position on the structure.
- The resulting structure on the right shows a balanced product with the nitrogen receiving electrons, denoted with lone pairs and a positive charge on the nitrogen.

**Diagram (b):**
- This mechanism also begins with a curved arrow from the hydroxyl oxygen to a proton.
- The next arrows depict electrons moving within the carbon-carbon double bond (C=C) and the nitrogen on adjacent atoms.
- The resultant structure shows a similar conversion with electron pairs and charges properly adjusted on the right side.

**Diagram (c):**
- An initial curved arrow is drawn from the oxygen to a proton, followed by a second arrow pointing back to the carbon-carbon double bond (resonance structure).
- The nitrogen then follows with an appeal to accept electrons.
- The product on the right side again shows the rearranged electrons with nitrogen having lone pairs and a positive charge.

**Diagram (d):**
- The last mechanism has an initial arrow from the oxygen to the proton.
- The arrows in the subsequent steps denote electron movement through the carbon-carbon bond to the nitrogen.
- The produced structure showcases the electron shift with the proper charges and lone pairs on the related atoms.

The student is asked to choose the correct mechanism with appropriate electron movement resulting in the accurate product formation from starting materials.
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Transcribed Image Text:### Question 14 **Which shows the correct curved arrows for the mechanism to convert the starting materials to the product?** #### Answer Choices: 1. (a) 2. (b) 3. (c) 4. (d) #### Detailed Explanation of Diagrams: Each of the diagrams (a), (b), (c), and (d) represent different proposed mechanisms for converting the starting material to the product. In each mechanism, curved arrows indicate the flow of electrons during the reaction. **Diagram (a):** - The mechanism shows an initial curved arrow from the lone pair on the hydroxyl oxygen (O) to the proton (H) in an adjacent carbon-carbon double bond (C=C). - Another curved arrow from the carbon-carbon double bond (C=C) to the nitrogen (N) indicates electron flow toward the nitrogen. - A final arrow from the nitrogen to an adjacent position on the structure. - The resulting structure on the right shows a balanced product with the nitrogen receiving electrons, denoted with lone pairs and a positive charge on the nitrogen. **Diagram (b):** - This mechanism also begins with a curved arrow from the hydroxyl oxygen to a proton. - The next arrows depict electrons moving within the carbon-carbon double bond (C=C) and the nitrogen on adjacent atoms. - The resultant structure shows a similar conversion with electron pairs and charges properly adjusted on the right side. **Diagram (c):** - An initial curved arrow is drawn from the oxygen to a proton, followed by a second arrow pointing back to the carbon-carbon double bond (resonance structure). - The nitrogen then follows with an appeal to accept electrons. - The product on the right side again shows the rearranged electrons with nitrogen having lone pairs and a positive charge. **Diagram (d):** - The last mechanism has an initial arrow from the oxygen to the proton. - The arrows in the subsequent steps denote electron movement through the carbon-carbon bond to the nitrogen. - The produced structure showcases the electron shift with the proper charges and lone pairs on the related atoms. The student is asked to choose the correct mechanism with appropriate electron movement resulting in the accurate product formation from starting materials.
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