Which of the following statements are correct for the titration of Fe2+ ion with standard Ce4+ ion? I- Indicator electrode potential is calculated using the Fe3+ half-reaction after calculating the equilibrium concentrations of Fe3+ and Fe2+ in the solution before the Ce4+ solution is added. II- Before the equivalence point, the indicator electrode potential is calculated using the Fe3+ half-reaction since [Fe3+] and [Fe2+] are known. III- At the equivalence point, the indicator electrode potential is the average of the E0 values of Fe3+ and Fe2+ IV- After the equivalence point, the indicator electrode potential is calculated using the Ce4+ half-reaction since [Ce3+] and [Ce4+] are known. A.II and IV B. I, II, III and IV C. I, III and IV D. II, III and IV

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Which of the following statements are correct for the titration of Fe2+ ion with standard Ce4+ ion?

I- Indicator electrode potential is calculated using the Fe3+ half-reaction after calculating the equilibrium concentrations of Fe3+ and Fe2+ in the solution before the Ce4+ solution is added.

II- Before the equivalence point, the indicator electrode potential is calculated using the Fe3+ half-reaction since [Fe3+] and [Fe2+] are known.

III- At the equivalence point, the indicator electrode potential is the average of the E0 values of Fe3+ and Fe2+

IV- After the equivalence point, the indicator electrode potential is calculated using the Ce4+ half-reaction since [Ce3+] and [Ce4+] are known.

A.II and IV
B. I, II, III and IV
C. I, III and IV
D. II, III and IV

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 6 steps with 4 images

Blurred answer
Knowledge Booster
Electrochemical Cells
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY