Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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When the following deuterium-labeled compound is treated with potassium tert-butoxide in N,N-dimethylformamide, a
single product is observed.
D
(CH3)3COK
dilute CH3CH2OK
CH3CH2OH
One product
Two products
DMF
When the same substrate is heated in the presence of dilute potassium ethoxide in ethanol, a mixture of two products is
formed. Provide the complete, detailed mechanism for each reaction and explain these results.
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Transcribed Image Text:When the following deuterium-labeled compound is treated with potassium tert-butoxide in N,N-dimethylformamide, a single product is observed. D (CH3)3COK dilute CH3CH2OK CH3CH2OH One product Two products DMF When the same substrate is heated in the presence of dilute potassium ethoxide in ethanol, a mixture of two products is formed. Provide the complete, detailed mechanism for each reaction and explain these results.
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