Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Electron Flow in SN2 Reaction Mechanism**

Curved arrows illustrate the flow of electrons in an SN2 reaction, providing insight into the mechanistic steps. Follow these arrows to predict the reaction's product. The diagram requires the inclusion of all lone pairs, and the use of wedge and dash bonds for indicating stereochemistry is essential. Inorganic byproducts should be ignored for clarity.

**Diagram Explanation:**

- The left structure shows a methoxide ion (CH₃O⁻) with three lone pairs on the oxygen.
- A blue curved arrow originates from the negatively charged oxygen and points towards the carbon atom bonded to chlorine, indicating a nucleophilic attack.
- The right structure depicts a secondary carbon center bonded to a hydrogen and methyl group, where chlorine is the leaving group. The chlorine has three lone pairs and is negatively charged as it leaves.
- The use of wedge (solid) and dash (hashed) bonds shows the stereochemistry around the chiral center.
- An arrow labeled "THF" points downward, suggesting tetrahydrofuran is the solvent.

This detailed representation aids in understanding electron flow and stereochemical changes in SN2 reactions.

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Transcribed Image Text:--- **Electron Flow in SN2 Reaction Mechanism** Curved arrows illustrate the flow of electrons in an SN2 reaction, providing insight into the mechanistic steps. Follow these arrows to predict the reaction's product. The diagram requires the inclusion of all lone pairs, and the use of wedge and dash bonds for indicating stereochemistry is essential. Inorganic byproducts should be ignored for clarity. **Diagram Explanation:** - The left structure shows a methoxide ion (CH₃O⁻) with three lone pairs on the oxygen. - A blue curved arrow originates from the negatively charged oxygen and points towards the carbon atom bonded to chlorine, indicating a nucleophilic attack. - The right structure depicts a secondary carbon center bonded to a hydrogen and methyl group, where chlorine is the leaving group. The chlorine has three lone pairs and is negatively charged as it leaves. - The use of wedge (solid) and dash (hashed) bonds shows the stereochemistry around the chiral center. - An arrow labeled "THF" points downward, suggesting tetrahydrofuran is the solvent. This detailed representation aids in understanding electron flow and stereochemical changes in SN2 reactions. ---
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