Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What is the reaction order and velocity constant and how are they determined from experimental data
Expert Solution
Step 1
Order of a reaction : in a chemical reaction with the concentrations of the reacting substances : the sum of all the exponents of the terms expressing concentrations of the molecules or atoms determining the rate of the reaction.
for example : 2A + B 3C
order = k[A]2[B]1
= 2+1
= 3
determination of order from the experimental data:
- the most common way to determine the order of a reaction by initial rate method.
in this method, the initial rate is measured by running a reaction several times with different initial reactant concentrations to determine the effect of the concentration on the rate.
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