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- H b) Determine the hybridization of each of the non-hydrogen atoms in the following molecules. Draw the hybridized electron energy diagram for each non-hydrogen atom (arrows on lines). :0: H H 1 -N-H 1 H H H Sp3 Sp3 :0-H L H H-C- -CICEN: -CI H H H -C-H C=CH = N=0: (07) zognero Ismo E abnod "wet pod" to "vnem oot" ead mots neri 1000 9 noi no siupsion no 981sro Istot of mua tauM enabbels gribrodnon IIA)-(ano/bels gnibnod tisH)-mots sent mi anonible sorelsV = 39 gniwollot sritto rose no sgiaro Ismol erts enime190 =D₂H] c) Draw an orbital picture (loops for orbitals) for each of the molecules above. Indicate the MED appropriate bond angles.What is the hybridization of the carbon indicated? (2 points) * H-CEN sp sp2 sp3 sp4What is the hybridization of the carbon indicated? (2 points) * H3C H H -OCH3 sp sp2 sp3
- 1.26 a. What is the hybridization of the central carbon of allene (H₂C=C=CH₂)? b. On a Lewis structure of allene, sketch the arrangement of the 2p orbitals on all of the carbons. c. Sketch the arrangement of the orbitals on a Lewis structure of allene. TU d. Each H CH group in allene defines a plane. What is the relationship of one H C H plane to the other?Divalent carbon species called carbenes are capable of fleeting existence. For example, methylene, :CH2, is the simplest carbene. The two unshared electrons in methylene can be either paired in a single orbital or unpaired in different orbitals. a. Identify the type of hybridization you expect carbon to adopt in singlet (spin-paired) methylene and draw an illustration of its orbital showing the location of its electrons. (4 marks) b. Identify the type of hybridization you expect carbon to adopt in triplet (spin-unpaired) methylene and draw an illustration of its orbital showing the location of its electrons.1.40 What kind of hybridization do you expect for each carbon atom in the following molecules? (a) H CH₂-CH3 (b) CH₂OH H N. 0 CH₂ CH₂-CH3 || CI H₂N T Procaine HO H H OH HO Vitamin C (ascorbic acid)
- 5. (2 points) Consider ethylene, and acetylene ethylene acetylene (a) Draw three-dimensional diagrams of each molecule. Label the hybridization of each carbon, and show all sigma and pi bonds. (b) Which of these molecules has the shortest bond length? Which has the longest? In each of these molecules, where is the largest electron density located in space?ula for the following line-angle structures (8 points): OH E. Provide the hybridization of the designated atoms in the following molecules (12 points) OH H3C H2C= There are two reactione chown holow The firet reaction nroceeds easily at elevatedAflatoxin B1 is a carcinogen that damages DNA molecules. Given the molecular structure: Fill in the lone pairs around each oxygen in the formula. [-3 points] b. Write the atomic orbital hybridization for each of the carbon and oxygen atoms in the formula. Classify each of the bonds shown in the formula as o (sigma) or t (pi). [-3 points] d. How many total o bonds are there in Aflatoxin B1? How many t bonds are there in Aflatoxin B1? Label each chiral carbon in Aflatoxin B1. How many total stereoisomers exist for a. С. е. Aflatoxin B1?
- What are the configurations of the two stereogenic carbon atoms in this molecule? CI H 5 6 O 3 2 4 H3C H A. (3R, 6R) B. (3R, 6S) OC. (3S, 6R) OD. (3S, 6S)1.10 Hybridized Atomic Orbitals What is the hybridization state of the central carbon atom in the structure below? A molecular structure of allene with SMILES string C=C=C. sp O sp2 sp3 Save for Later5. What is the hybridization of each carbon atom in the following structure? (10 points) HO