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Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter14: Conjugated Compounds And Ultraviolet Spectroscopy
Section14.SE: Something Extra
Problem 41AP: Although the Diels–Alder reaction generally occurs between an electronrich diene and an...
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Mono addition of HBr to conjugated dienes leads to multiple products, and a given addition product can arise from more than
one conjugated diene. Two allylic bromide products can be synthesized from a diene. From the list given, identify the pair of
dienes wherein each diene can serve as a precursor for both of the addition products.
Note that not all possible products are shown.
Diene
HBr
Identify the diene precursors.
H3C
مک می
H3C.
Br
CH3
+
Br
H3C
Two monoaddition products
CH3
CH3
Transcribed Image Text:Mono addition of HBr to conjugated dienes leads to multiple products, and a given addition product can arise from more than one conjugated diene. Two allylic bromide products can be synthesized from a diene. From the list given, identify the pair of dienes wherein each diene can serve as a precursor for both of the addition products. Note that not all possible products are shown. Diene HBr Identify the diene precursors. H3C مک می H3C. Br CH3 + Br H3C Two monoaddition products CH3 CH3
H₂C
H3C
H₂C
H₂C
H₂C
H3C
CH3
شکست میگه
H3C
CH3
H3C.
CH3
CH3
L
CH3
CH3
CH3
CH3
CH3
+
ma
CH3
+
+
H3C
H3C
H3C
H3C
H3C
CH3
H3C
CH3
CH₂
CH3
CH₂
CH₂
CH₂
CH₂
CH3
CH3
CH₂
CH3
Transcribed Image Text:H₂C H3C H₂C H₂C H₂C H3C CH3 شکست میگه H3C CH3 H3C. CH3 CH3 L CH3 CH3 CH3 CH3 CH3 + ma CH3 + + H3C H3C H3C H3C H3C CH3 H3C CH3 CH₂ CH3 CH₂ CH₂ CH₂ CH₂ CH3 CH3 CH₂ CH3
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