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What do you mean by the term equilibrium partition coefficient?
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- Differentiate between Fermi level and Fermion.18. Which of the following is the definition of internal energy of a system? a.it is the sum of the kinetic energy of all of its components b.it is the sum of the rotational, vibrational, and translational energies of all of its components c.lt refers only to the energies of the nuclei of the atoms of the component molecules d.It is the sum of the potential and kinetic energies of the componentsDifferentiate between distribution ratio (D) and partition coefficient (K,).
- JustifyTrouton"s rule. What are the sources of discrepancies?Discuss the relation between the thermodynamic and statistical definitions of entropy.The internal energy of a system A None of these В is the sum of the rotational, vibrational, and translational energies of all of its components refers only to the energies of the nuclei of the atoms of the component molecules D is the sum of the kinetic energy of all of its components E) is the sum of the potential and kinetic energies of the components
- Name the thermodynamic state function that is a measure of randomness or can also be defined as "Energy spontaneously disperses from being localized to becoming spread out if it is not hindered from doing so."Briefly describe the contributions of Walter Nernst, T. W. Richards, Max Planck and G. N. Lewisin the development of the third law of thermodynamics.By what means can the internal energy of a closed system increase?
- We discussed in class (several times) how the Boltzmann distribution can be used to relate the relative populations of two states differing in energy by AU. Suppose you are given a vial containing a solution of glucose in water (don't ask why this would happen). For the purpose of this question, glucose exists in one of two conformations-"chair" or "boat"-with an energy difference (AU) of 25.11 kJ mol1 between them. 1. What would be the proportion of molecules in the "boat" conformation at 310K? 2. Thinking back to our discussion of the individual sources of energy that go into the potential energy calculation for a molecule (e.g. Upond Uangle, Uelectrostatic. etc), give a plausible explanation of why the "boat" conformation is less stable. H он "Chair" OH "Вoat" но но но- HO. H. HO. HO H. HO. OHBriefly describe the contributions of Walter Nernst, T. W. Richard's, Max Planck and G. N. Lewis in the development of the third law of thermodynamics.(1) The molecules in a thermally equilibrated isolated system are confined to just the two (non-degenerate) energy levels. lowest (a) Write down an expression for the partition function q of this system if the energy levels are separated by an amount ɛ. (b) If q = 1.142, determine the temperature of the system if the two energy levels are separated by 8 kJ/mol. (c) What is q in the limit of very high temperatures?