Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Related questions
Concept explainers
Question
We dissolve 2.66 g of an unknown acid, HA, in enough water to produce 25.0 mL of solution. The pH of
this solution is 1.44. We titrate this solution with a 0.250 M NaOH solution and we need 33.3 mL of this
0.250 M NaOH solution to reach the equivalence point. The temperature is 25.0 ◦C throughout.
(a) What is the molar mass of HA?
(b) What is the dissociation constant, Kb, of A−(aq)?
(c) What would be the pH of a 2.222 M solution of A−(aq)?
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by stepSolved in 4 steps with 4 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Buffer capacity is a measure of a buffer solution's resistance to changes in pH as strong acid or base is added. Suppose that you have 145 mL of a buffer that is 0.100 M in both propanoic acid (C2H;COOH) and its conjugate base (C2H5CO0). Calculate the maximum volume of 0.420 M HCl that can be added to the buffer before its buffering capacity is lost. mLarrow_forwardThe sample of 25.0 mL of 0.0200 M NH3 is titrated with a 20.0 mL of 0.0150 M HCl solution. (a) Show the reaction between NH3 and H+. (b) What is the final volume after two solutions were mixed? (c) What is the final molarity of NH3 after the reaction with H+? (d) What is the pH after 20.0 mL of the HCl solution is added? (Ka of NH4+ is 5.6 x 10–10)arrow_forwardConsider the following information to answer the questions below. A volume of 10.00 mL of 0.100 M acetic acid (HC2H3O2) is titrated with 0.107 M sodium hydroxide solution. Given the chemical equation below. Calculate the volume (in milliliters) of NaOH needed to reach the equivalence point of the titration. HC2H3O2(aq) + NaOH(aq) -> H2O (l) + NaC2H3O2(aq)arrow_forward
- Given that Ka’s for hydrofluoric acid (HF) and boric acid (H3BO3) are 6.3 × 10^–4and 5.4 × 10^–10, respectively, calculate the pH of the following solutions: (a)The mixture from adding 50 mL 0.2 M HF to 50 mL 0.5 M sodium borate (NaH2BO3). (b)The mixture from adding an additional 150 mL 0.2 M HF to the solution in (a), i.e., a total of 200 mL 0.2 M HF was added to 50 mL 0.5 M NaH2BO3.arrow_forward1. the temperature for each solution is carried out at approximately 297 K where Kw = 1.00 x 10 ^-14 (a) 0.20 g of hydrogen chloride (HCl) is dissolved in water to make 4.5 L of solution. What is the pH of the resulting hydrochloric acid solution? (b) 0.70 g of sodium hydroxide (NaOH) pellets are dissolved in water to make 3.0 L of solution. What is the pH of this solution ?arrow_forwardA buffer solution is made that is 0.409 M H2S and 0.409 M in NaHS. If Ka1 for H2S is 1.00x10^-7, what is the pH of the buffer solution? pH = Write the net ionic equation for the reaction that occurs when 0.087 mol NaOH is added to 1.00 L of the buffer solution. (Use the lowest possible coefficients. Omit states of matter.)arrow_forward
- 13. A 60.00 mL sample of 0.075 M sodium benzoate (NaC7H5O2) was titrated with 0.050 M HCl. What is the pH of the solutionafter 10.00 ml of HCl is added?(a) 4.19(b) 5.09(c) 5.74(d) 6.2414. What is the ratio of moles of benzoate (C7H5O2‒) to benzoic acid (HC7H5O2) in the solution that results from thecombination of the NaC7H5O2 and HCl in the problem above?(a) 8(b) 0.125(c) 0.0040(d) 0.00050arrow_forwardA buffer is prepared by adding 5.0 g of ammonia, NH3, and 20.0 g of ammonium chloride, NH4Cl, to enough water to form 2.50 L of solution. (a) What is the pH of the buffer? (b) Write the complete ionic equation for the reaction that occurs when a few drops of nitric acid are added to the buffer. (c) Write the complete ionic equation for the reaction that occurs when a few drops of potassium hydroxide solution are added to the buffer.arrow_forwardTwenty millimeters of 0.50N HOAc is diluted with water to 100mL, and the resulting solution is titrated with 0.50N HOAc. Calculate the pH value (a) at the start, (b) when 0.8 ml of the NaOH has been added, (c) at the equivalence point (when 20mL of NaOH has been added, (d) when 30mL of the NaOH has been added. Ka=1.8x10^-5arrow_forward
- A solution is prepared that is initially 0.26M in hydrofluoric acid (HF) and 0.25M in potassium fluoride (KF). Complete the reaction table below, so that you could use it to calculate the pH of this solution. Use x to stand for the unknown change in [H₂O*]. You can leave out the M symbol for molarity. initial change final [HF] 0 П [F] 0 0 0 [H₂O*] 0 0 0 Xarrow_forwardA solution is prepared that is initially 0.13M in acetic acid (HCH3CO₂) and 0.24M in potassium acetate (KCH3CO₂). Complete the reaction table below, so that you could use it to calculate the pH of this solution. Use x to stand for the unknown change in initial change final [HCH,CO₂] 0 [H₂0]. You can leave out the M symbol for molarity. [cH,co,] 0 L [H₂O] 0 0 0 plo X Garrow_forward(a) Calculate the acetate ion concentration in a solution prepared by dissolving 8.70×10-3 mol of HCl(g) in 1.00 L of 1.10 M aqueous acetic acid (Ka = 1.80×10-5). (b) Calculate the pH of the above solution. Give your answer to two decimal places.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning 
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY