Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Water and acetonitrile, CH3CN, are miscible (can be mixed in any proportions). However, when water and acetonitrile are mixed, the volumes are not additive (the total volume of the resulting solution is not equal to the sum of the pure liquid volumes). For example, when 100.0 mL of water and 100.0 mL of CH3CN(1), are mixed at 20 °C, the total volume of the solution is 192.0mL, not 200.0 mL. a. Provide an explanation for this phenomenon. b. Calculate the molarity, molality and mol fraction of CH3CN in a solution prepared by mixing 100.0 mL of water and 100.0 mL of CH3CN(1) at 20 °C. The total volume of the mixture is 192.0 mL and the densities of water and acetonitrile are 0.998 g/mL and 0.782 g/mL, respectively, at this temperature. c. [When 70.0 g H2O and 190.0 g CH3CN(1) are mixed, to resulting solution has a density of 0.860 g/mL at 20 °C. Calculate the volumes of the pure liquid samples and the solution, and show that the pure liquid volumes are not additive.

Water and acetonitrile, CH3CN, are miscible (can be mixed in any proportions). However, when water and acetonitrile are mixed, the volumes are not additive (the total volume of the resulting solution is not equal to the sum of the pure liquid volumes). For example, when 100.0 mL of water and 100.0 mL of CH3CN(1), are mixed at 20 °C, the total volume of the solution is 192.0mL, not 200.0 mL. a. Provide an explanation for this phenomenon. b. Calculate the molarity, molality and mol fraction of CH3CN in a solution prepared by mixing 100.0 mL of water and 100.0 mL of CH3CN(1) at 20 °C. The total volume of the mixture is 192.0 mL and the densities of water and acetonitrile are 0.998 g/mL and 0.782 g/mL, respectively, at this temperature. c. [When 70.0 g H2O and 190.0 g CH3CN(1) are mixed, to resulting solution has a density of 0.860 g/mL at 20 °C. Calculate the volumes of the pure liquid samples and the solution, and show that the pure liquid volumes are not additive.

Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter6: Solutions And Colloids
Section: Chapter Questions
Problem 6.111P: 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more...
See similar textbooks
icon
Related questions
Question
Water and acetonitrile, CH3CN, are miscible (can be mixed in any proportions). However, when water and acetonitrile are mixed, the volumes are not additive (the total volume of the resulting solution is not equal to the sum of the pure liquid volumes). For example, when 100.0 mL of water and 100.0 mL of CH3CN(I), are mixed at 20 °C, the total volume of the solution is 192.0mL, not 200.0 mL. a. Provide an explanation for this phenomenon. b. Calculate the molarity, molality and mol fraction of CH3CN in a solution prepared by mixing 100.0 mL of water and 100.0 mL of CH3CN(1) at 20 °C. The total volume of the mixture is 192.0 mL and the densities of water and acetonitrile are 0.998 g/mL and 0.782 g/mL, respectively, at this temperature. c. When 70.0 g H2O and 190.0 g CH3CN(1) are mixed, to resulting solution has a density of 0.860 g/mL at 20 °C. Calculate the volumes of the pure liquid samples and the solution, and show that the pure liquid volumes are not additive.
Transcribed Image Text:Water and acetonitrile, CH3CN, are miscible (can be mixed in any proportions). However, when water and acetonitrile are mixed, the volumes are not additive (the total volume of the resulting solution is not equal to the sum of the pure liquid volumes). For example, when 100.0 mL of water and 100.0 mL of CH3CN(I), are mixed at 20 °C, the total volume of the solution is 192.0mL, not 200.0 mL. a. Provide an explanation for this phenomenon. b. Calculate the molarity, molality and mol fraction of CH3CN in a solution prepared by mixing 100.0 mL of water and 100.0 mL of CH3CN(1) at 20 °C. The total volume of the mixture is 192.0 mL and the densities of water and acetonitrile are 0.998 g/mL and 0.782 g/mL, respectively, at this temperature. c. When 70.0 g H2O and 190.0 g CH3CN(1) are mixed, to resulting solution has a density of 0.860 g/mL at 20 °C. Calculate the volumes of the pure liquid samples and the solution, and show that the pure liquid volumes are not additive.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 7 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Group 1 Elements
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
Chemistry
ISBN:
9781285853918
Author:
H. Stephen Stoker
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
SEE MORE TEXTBOOKS