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- 18.12 Identify the compound in each pair that has the higher boiling point. Explain. a. CH3-CH,-CH,-CH3 or CH3-CH2 CH,NH, b. CH3-NH, or CH3-CH2-NH2 NH2 c. CH3-CH2 -CH2-OH or CH3-CH-CH;2. Methadone, a narcotic analgesic (shown below as the amine), is dispensed as its hydrochloride salt. Explain the use of the salt rather than the amine. Use the structure shown and convert it to the HOLT 24th hydrochloride salt. N-CH3 H3C CHIA peop Methadone GHL aco Hot 40Assign a common name to each of the following amines. 17-16 a. CH3-CH-CH3 NH2 b. H2N-CH2-CH,-CH2-CH; c. CH3-CH2-Ņ-CH,-CH3 ČH,-CH3 d. CH3-CH2-CH2–NH-CH-CH3 ČH3
- Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OHDraw the major product formed by treating each amine with excess CH3I, followed by Ag,0, and then heat. -CH,CHCH3 NH2 а. b. C. H2NWhat amide(s) can be used to prepare each amine by reduction?
- Give the major product for the reaction. Pyrrolidine is a secondary amine. CH CH O CH CH! O OH CH2 O CH. I CH.CH Ї TCH CHE OH CH CH₂CH₂ CH.CH CH.OH2 0= RO pyrrolidine. 2 GH CH2 3 HCI H,0 TOH OH: CH₂CH₂ TCH CH: CH₂CH. CH₂CH₂1. What is the product of the reaction? 1) LAH 2) Hо* но OH а. b. OH с. HO. HO. d. 2. Which amine is expected to be least soluble in HzO? `NH2 а. c. N. b. d. ZIDraw the structure of the amine salt produced when each of the following amines reacts with HCl. 6-50 a. CH3-CH2-CH2-NH2 b. CH3-NH-CH3 CH3 c. CH-CH-CH2-NH2 d. NH-CH-CH
- Amines and Amides 5. Base Hydrolysis a. Acetamide b. Benzamide Questions and Problems Q6 You have unknowns that are a carboxylic acid, an ester, and an amine. Describe how you would distinguish among them. రెండం we can acid an amine. Carlouxylicacid S have Dt ester s naue Sightiy ncutra DH and amine S Waue basic DH that 15jmore thon 7 Based on the OH of the Soutions distinquish Carooxy lic ester and an value Less than neutra 14416.13 Name each of the following amines by one of the methods used in Exercises 16.7, 16.9, and 16.11: a. CH₁₂ CH-C-NH, C. NH, CH₁₂ b. CH,CH,-N-CH₂CH, d. Cl CH, NH CH,CHCH,CHCH,17-50 Draw the structure of the amine salt produced when each of the following amines reacts with HCl. a. CH3-CH,-CH2-NH2 b. CH3-NH-CH3 CH3 c. CH,-CH-CH;-NH, d.[NH-CH;-Ch -NH-CH-CH