Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Solutions
Procedure:
1. Prepare 50 mL of a 0.100 M solution of LiCl.
2. Using this stock solution, prepare a series of solutions (20 mL each) with the following concentrations:
0.0500 M, 0.0250 M, 0.0125 M, and0.00625 M. The dilutions should leave ~30 mL of the 0.100 M
stock solution to finish the series.
(Note that each solution in the series is ½ the concentration of the previous solution.)
3. Using the information in the tables below, plot conductivity (mS cm') vs. concentration (mol/L) using Excel
(or other plotting software) and apply a linear regression analysis to the plot.
4. Repeat steps 1-3 for formic acid.
LICI
Formic Acid
ms cm
10.66
mol/L
0.10000
ms cm
1.79
1.60
mol/L
0.10000
7.75
0.05000
0.05000
6.30
0.02500
1.50
0.02500
5.57
0.01250
1.45
0.01250
5.21
0.00625
1.43
0.00625
Questions:
1. Determine the mass of LİCI (42.394 g/mol) required for Step l.
2. Show your calculations for the volume of 0.100 M LİCI required for each dilution in Step 2.
(HINT: dilution law: M¡Vi = M¿V2)
3. Submit your two clearly labeled plots (including their linear fits) from Excel (or other plotting
software). There is a short video on D2L on how to plot using Excel.
4. Which compound is the stronger electrolyte? What do you believe to be the major factor accounting for
the difference?
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Transcribed Image Text:Solutions Procedure: 1. Prepare 50 mL of a 0.100 M solution of LiCl. 2. Using this stock solution, prepare a series of solutions (20 mL each) with the following concentrations: 0.0500 M, 0.0250 M, 0.0125 M, and0.00625 M. The dilutions should leave ~30 mL of the 0.100 M stock solution to finish the series. (Note that each solution in the series is ½ the concentration of the previous solution.) 3. Using the information in the tables below, plot conductivity (mS cm') vs. concentration (mol/L) using Excel (or other plotting software) and apply a linear regression analysis to the plot. 4. Repeat steps 1-3 for formic acid. LICI Formic Acid ms cm 10.66 mol/L 0.10000 ms cm 1.79 1.60 mol/L 0.10000 7.75 0.05000 0.05000 6.30 0.02500 1.50 0.02500 5.57 0.01250 1.45 0.01250 5.21 0.00625 1.43 0.00625 Questions: 1. Determine the mass of LİCI (42.394 g/mol) required for Step l. 2. Show your calculations for the volume of 0.100 M LİCI required for each dilution in Step 2. (HINT: dilution law: M¡Vi = M¿V2) 3. Submit your two clearly labeled plots (including their linear fits) from Excel (or other plotting software). There is a short video on D2L on how to plot using Excel. 4. Which compound is the stronger electrolyte? What do you believe to be the major factor accounting for the difference?
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