Using molecular orbital theory, arrange the following in order of decreasing stability He2, H2, H2+, He2+ a. He2 > H2+> He2+ > H2 b. He2 > H2+, He2+ > H2 c. H2 > H2+> He2+ > He2 d. H2 > H2+, He2+ > He2 e. He2+ > H2+ > H2 > He2
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Using molecular orbital theory, arrange the following in order of decreasing stability
He2, H2, H2+, He2+
a.
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He2 > H2+> He2+ > H2
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b.
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He2 > H2+, He2+ > H2
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c.
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H2 > H2+> He2+ > He2
|
d.
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H2 > H2+, He2+ > He2
|
e.
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He2+ > H2+ > H2 > He2 |
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- s Using the molecular orbital model, identify the correct (valence) electron configurations for the following diatomic species. O CN O N2 O CN OCN+ 02 A. (025)?(02s*)?(n2p)* B. (025)?(025*)?(02p)?(n2p)*(n2p*)3 c. (025) (02s*)?(n2p)*(02p)²(n2p*)! D. (025)?(02s*)?(n2p)*(02p)! E. (025)?(025*)?(n2p)*(02p)? F. (02s)2(02s*)?(02p)?(n2p)*(n2p*)? G. (025)?(02s*)?(02p)²(n2p)ª(n2p*)* 1 ar ecWhich is the correct electron configuration for B2+ according to the molecular orbital theory? (5B) A. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz2 B. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1 C. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz1 D. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1π2py19. Which of the following molecules would you expect to have a dipole moment of zero? a. CH3CH3 b. H₂C=O e. H₂C=CH2 f. H₂C=CHBr g. BeCl₂ h. BF3 C. CH₂Cl2 d. NH3
- Molecule or Polyatomic BrF5 2- SiO3² NH4CIO₂ K3PO4 Lewis structure 3 K+ F Br. H H-N-H H .. ܀ :O: F o=d-0: : 0: + :O: 2- 3- Hybrid- ization AXE sp³d² AX-E 2 sp² AX3 3 sp AX4 sp AX₂E₂ sp³ AX4 Electron pair geometry Molecular shape octahedral square pyramidal trigonal planar trigonal planar tetrahedral tetrahedral tetrahedral bent tetrahedral tetrahedral Bond angles (eq) 90° (ax) 90° all 120° all ~109.5° all ~109.5° Bond Polarity Molecular Polarity if the molecule is polar, add a dipole arrow if not polar, state so and why H H T S F H OP F cisoсс с C-C= C C-C C- C C a. Complete the formula, number the carbon atoms and name the molecule b. Draw and label in terms of the overlapping hybrid orbitals forming each bond c. Identify the hybrid orbitals forming each bond For your answers for letters d,e,f, give the number of the C atom (from a) only (ex. C10 - C11) d. Which C to C bond is the strongest e. Which C to H bond is the most polar f. Which C to C bond is the least free to rotate g. What is the mobile bond orderA Moving to another question will save this response. Question 1 Which is the correct molecular orbital diagram for O 2 ion? Oo 2s 1lo 2s t 1 T2p 1 1.t102p tI 2p t o 2s 1ļo 2s 11 m2p 1102p 1 1 72p tt t o 2s 1lo 2s 11 T|2p 1 1. t102p t 2p t1 o 2s 1ļo 2s 1 2p ↑ 1. t L. t I o2p ↑ 1 12p t O o 2s 1io 2s t I 12p ↑ 1 02p ↑ 1 12p t 1.t A Moving to another question will save this response.
- VSEPR: Molecular Geometry 1. For the following molecules: 1) draw a Lewis Dot structure, including contributing resonance structures, if present; 2) use VSEPR to draw an appropriate structure; 3) give an appropriate designation for the ideal molecular geometry; 4) describe any deviations to the ideal molecular geometry; *don't worry about corrections for e and h. g. HOCI h.* SO;2 i. NO2*1. Determine the bond order & magnetic behavior of the molecules: а. В* bond order: Atomic orbitals Molecular Atomic orbitals Atomic Molecular Atomic orbitals orbitals orbitals orbitals magnetic: b. Ne22+ bond order: 2p 2p 2p 2p magnetic: с. С2 Energy bond order: magnetic: d. F22- 2s 2s 2s 2s bond order: B2, C2, N2 02, F2, Ne, magnetic: 2011 Pearson Education, In е. Оz* bond order: magnetic:What is the hybridization of the indicated atoms in the following compound? Ol=sp; 11=sp²; III =sp³; IV =sp² Ol=sp²; 11=sp; III =sp²; IV -sp³ O 1-sp³; 11-sp²; III -sp; IV =sp² OI=sp²; 11-sp3; III =sp²; IV =sp OI=sp²; 11 =sp²; III=sp²; IV -sp³ |||||| O=C=N/ C-H HH
- a. H₂C-CH₂ 20 b. H₂C- C. d. Br Br e. f. _CH₂ H₂C 0 CH-CH₂ HỌC—NH HC C-CH₂-OH HỌC NH, 37. For each molecule in Problem 36, describe the orbitals that are used to form every bond to each of the indicated atoms (atomic s, p, hybrid sp, sp², or sp).Molecule C2H2 SFs- NO3- Lewis structure include lone pairs & formal charges on each atom Resonance structures don't have to include lone pairs; write N/A if there are none Electron Geometry Hybridization on central atom Overlapping orbitals O: O: include value of n in the orbital name (e.g. 1s, not s). Write N/A if that kind T: of bond is not present in T: the molecule Molecular Geometry Bond angle(s) include < as necessary 3D structure and polarity don't have to include lone pairs; draw the dipole arrow on the molecule or write "non- polar"VSEPR: Molecular Geometry 1. For the following molecules: 1) draw a Lewis Dot structure, including contributing resonance structures, if present; 2) use VSEPR to draw an appropriate structure; 3) give an appropriate designation for the ideal molecular geometry; 4) describe any deviations to the ideal molecular geometry; *don't worry about corrections for e and h. d. SF4 e.* CHŞN f. H;CO