Use the logarithmic Arrhenius equation and the following data showing the dependence of temperature and reaction rate constant k to predict the activation energy barrier (E₂) for the reaction shown. Hint: try graphing In(k) against 1/T from the data in the table and estimate the intercept, which is In(A), and the slope, which is Ea/R. In case you get stuck, you can use the Arrhenius factor for this reaction (A = 8.1 x 10⁹ mol-¹Ls-¹) and substitute it into the equation. 2NO2 (g) T(K) 673 683 693 703 713 O E = 1.2 x 105 kJmol-1 O E₂8.314 JK ¹mol-1 O E₂ -119601 Jmol-¹ O E₂ = 7.7 x 106 J O E₂ 1.2 x 10² kJmol-1 = 2NO (9) k (mol ¹Ls ¹) 7.8 10 14 18 24 + O2 (g)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Use the logarithmic Arrhenius equation and the following data showing the dependence of
temperature and reaction rate constant k to predict the activation energy barrier (E₂) for the reaction
shown. Hint: try graphing In(k) against 1/T from the data in the table and estimate the intercept, which
is In(A), and the slope, which is E₂/R. In case you get stuck, you can use the Arrhenius factor for this
reaction (A = 8.1 x 10⁹ mol-¹Ls ¹) and substitute it into the equation.
2NO(g)
+ O2 (g)
2NO2 (9)
T(K)
673
683
693
703
713
O Ea 1.2 x 105 kJmol-1
O E₂8.314 JK ¹mol-1
O E₂ -119601 Jmol-¹
O E₂
7.7 x 106 J
1.2 x 10² kJmol-¹
O Ea
O E₂ = 0.12 kJ
k (mol ¹Ls ¹)
7.8
10
14
18
24
Transcribed Image Text:Use the logarithmic Arrhenius equation and the following data showing the dependence of temperature and reaction rate constant k to predict the activation energy barrier (E₂) for the reaction shown. Hint: try graphing In(k) against 1/T from the data in the table and estimate the intercept, which is In(A), and the slope, which is E₂/R. In case you get stuck, you can use the Arrhenius factor for this reaction (A = 8.1 x 10⁹ mol-¹Ls ¹) and substitute it into the equation. 2NO(g) + O2 (g) 2NO2 (9) T(K) 673 683 693 703 713 O Ea 1.2 x 105 kJmol-1 O E₂8.314 JK ¹mol-1 O E₂ -119601 Jmol-¹ O E₂ 7.7 x 106 J 1.2 x 10² kJmol-¹ O Ea O E₂ = 0.12 kJ k (mol ¹Ls ¹) 7.8 10 14 18 24
Expert Solution
steps

Step by step

Solved in 4 steps with 3 images

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY