
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Use the ligand information above to determine the coordination number for the central
Na4[Nb(ox)2Cl2] Transition Metal Coordination Number:
[Os(NH3)3(OH)3]OH Transition Metal Coordination Number:
Na2[Mo(EDTA)] Transition Metal Coordination Number:
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- Consider the following complex ions: [NiBr6]4-,[Ni(H2O)6]3+ and [Ni(CO)6]3+. Using the Crystal Field Theory, in each case (i) draw d-orbital electron configurations (ii) determine the number of unpaired electrons (iii) predict the magnetic properties (iv) state and explain the complex is high-spin or low-spin.arrow_forward[Fe(OH₂)6]²+ is paramagnetic whereas [Fe(CN)6]4 is diamagnetic. Which of the following provides the best explanation for this? As a weak field ligand, H₂O induces a larger A, than CN, which is a strong field ligand. [Fe(OH₂)6]²+ is a positively charged complex whereas [Fe(CN)6]4 is a negatively charged complex. O [Fe(OH₂)6]²+ has fewer paired electrons because the pairing energy is larger than A.。. O [Fe(OH₂)6]²+ is a low spin complex while [Fe(CN)6]4 is a high spin complex.arrow_forwardWhat is the transition metal-containing product for the following reaction, where [Rh(CO)Br3]2- is a square-planar complex? [Rh(CO)Br3]2- + CO(g) --> ? Group of answer choices [RhBr4]3- an equal mixture of cis- and trans-[Rh(CO)2Br2]- trans-[Rh(CO)2Br2]- cis-[Rh(CO)2Br2]-arrow_forward
- Write the valence electron configuration for the cobalt ions in the complexes [Co(H2O)6]2+ and draw labelled crystal field splitting diagram (relative to the spherical ion) and calculate the magnetic moment, µ(spin-only) of the cobalt ion in the complexes and as a free metal ion.arrow_forwardDetermine the oxidation state of the transition metal in each of these coordination compounds. compound K₂ [ZnCI, (CO),] Na, [CrBr, (H₂0)] [PICI, (NH₂), ]Br oxidation state of the transition metal 0 □arrow_forwardAnswer the following questions about the transition metals complexes with the chemical formulas [Co(en)3]3+and [CoCl6]3- Would either the low-spin or high-spin configuration result in a paramagnetic complex? One of the complexes is orange while the other is blue. Which cobalt complex is which color? Justify your answer and identify which color the complex will absorb based on its color.arrow_forward
- A) Using a cobalt (III) ion as the central metal atom, and with chloride ions (Cl-) and ammonia (NH3) molecules as the ligands, draw both isomers of the coordination complex that will exhibit fac/mer isomerism. B) Using a platinum (II) ion as the central metal atom, with chloride ions and ammonia molecules as the ligands, draw both isomers of the coordination complex that will exhibit cis/trans isomerism. Platinum (II) forms four coordinate bonds.arrow_forwardNonearrow_forwardAssume each of the following complexes has a +2-charged metal center. Which complex contains at least one hydride ligand and has the correct overall charge for the complex? Group of answer choices [Hf(bipy)(CO)2(H)2] [Hf(bipy)(CO)2(H2)] [Hf(bipy)(CO)2(H2)]2+ [Hf(bipy)(CO)2(H)2]2+arrow_forward
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