
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Three bottles of aqueous solutions are discovered in an abandoned lab. The solutions are green, yellow, and purple. It is known that three complex ions of chromium (III) were commonly used in the lab: [??(?2?)6]+3, [??(??3)6]+3, and [??(?2?)4??2]+. Determine the likely identity of each of the colored solutions
![Three bottles of aqueous solutions are discovered in an abandoned lab. The solutions are
green, yellow, and purple. It is known that three complex ions of chromium (III) were
commonly used in the lab: [Cr(H20)c]+³, [Cr(NH3)6]+3, and [Cr(H20)4C\2]+. Determine the
likely identity of each of the colored solutions](https://content.bartleby.com/qna-images/question/f274a205-130b-4933-be31-61debdbfcc0a/c730222b-8e2e-43fd-a276-6e1ea2dc468d/44ef92_thumbnail.png)
Transcribed Image Text:Three bottles of aqueous solutions are discovered in an abandoned lab. The solutions are
green, yellow, and purple. It is known that three complex ions of chromium (III) were
commonly used in the lab: [Cr(H20)c]+³, [Cr(NH3)6]+3, and [Cr(H20)4C\2]+. Determine the
likely identity of each of the colored solutions
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- Cr(aq) + 3 e Cr(s) Zn²(aq) + 2 e → Zn(s) 2 H₂O() +2 e → H₂(g) + 2 OH(aq) Mn2(aq) + 2 e A(an) + 3 e Mn(s) Al(s) 7. All of the following statements concerning ligand field theory are true EXCEPT A. in low-spin complexes, electrons are concentrated in the day, dys, and dr orbitals. B. in an isolated atom or ion, the five d orbitals have identical energy. C. low-spin complexes contain the maximum number of unpaired electrons. D. the crystal field splitting is larger in low-spin complexes than high-spin complexes. E. the energy difference between d orbitals often corresponds to an energy of visible light. 8. All of the following complexes will be colored (in the visible) EXCEPT A. [Co(en)]2+ B. [Fe(CN)6] C. [Ni(H₂O)]²+ D. [Cd(NH3)4]2+ 9. A positron has a mass number of a(n) a. 0; 1+; proton b. 1; 2+; proton c. 0; 1+; electron d. 1; 2+; electron e. 0; 0; proton -0.76 -0.83 -1.18 -1.66 a. [Cr(CO)6]C13 b. [Cu(OH)4(NH3)2] c. K4[Mn(CN)6] d. [Pt(en)3] (NO3)4 e. [Pt(NH3)2(OH₂)CIJ3PO4 10. In which…arrow_forwardThe coordination complex, [Fe(CN)5(NO)]2, displays linkage isomerism. Draw the structural formula of the complex ion for each of the linkage isomers. Explicitly draw all H atoms. Do not include charges. Non-bonding electrons will be ignored. Do not include counter-ions, e.g., Na", T, in your answer. Separate structures with + signs from the drop- down menu. Treat "NO" as the NOt ion.arrow_forward
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