The van der Waals equation is given by, a (v-b)= kT Here, a and b are constant. k to determine the v -b Use the relations T P and expression for the change in temperature when the gas expands from initial volume V, to final volume V,. N'a 1 1 (a) T, – T, =- + C, (V, V, N'a 1 1 (b) T, – T, = %3D C, (V, V, N? (c) T, -T, =- 1 1 %3D (6) 7; -7; = ) aC, ( V, V, Na ( 1 V V2 1 Т, —т, Cy

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The van der Waals equation is given by,
a
P+ (v-b) = kT
Here, a and b are constant.
k
to determine the
v-b
Use the relations
T
OT
|-P and
av
expression for the change in temperature when the gas expands from initial volume V, to
final volume V,.
N'a 1
(а) Т, — Т, 3
C, (V, V,
1
N'a 1
1
(b) Т, —Т,
C, (V, V
N?
(с) Т, —Т, —
1
1
aC, (V,
Na? ( 1
V
1
(d) T, – T, = -
C, ( ½,
V, V,
Transcribed Image Text:The van der Waals equation is given by, a P+ (v-b) = kT Here, a and b are constant. k to determine the v-b Use the relations T OT |-P and av expression for the change in temperature when the gas expands from initial volume V, to final volume V,. N'a 1 (а) Т, — Т, 3 C, (V, V, 1 N'a 1 1 (b) Т, —Т, C, (V, V N? (с) Т, —Т, — 1 1 aC, (V, Na? ( 1 V 1 (d) T, – T, = - C, ( ½, V, V,
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