The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) PTotal (kPa) Pso₂Cl₂ Ps0₂ Pcl₂ 0 11.07 3 14.79 6 17.26 9 12 18.90 19.99 15 20.71 Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as 5, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂cl₂ + Pso₂ + Pcl₂ = (Po-5)+5+5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction.

The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) PTotal (kPa) Pso₂Cl₂ Ps0₂ Pcl₂ 0 11.07 3 14.79 6 17.26 9 12 18.90 19.99 15 20.71 Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as 5, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂cl₂ + Pso₂ + Pcl₂ = (Po-5)+5+5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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