The thickness of the chromium plate on an auto fender is determined by dissolving a 30.0-cm2 section in acid and oxidizing Cr3+ to Cr2O7 2-with peroxydisulfate. After removing excess peroxydisulfate by boiling, 500.0 mg of Fe(NH4 )2 (SO4 )2•6H2O is added, reducing the Cr2O7 2- to Cr3+ . The excess Fe2+ is back titrated, requiring 18.29 mL of 0.00389 M K2Cr2O7 to reach the end point. Determine the average thickness of the chromium plate given that the density of Cr is 7.20 g/cm3 . Note: thickness = volume /area

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The thickness of the chromium plate on an auto fender is

determined by dissolving a 30.0-cm2

section in acid and

oxidizing Cr3+ to Cr2O7

2-with peroxydisulfate. After removing

excess peroxydisulfate by boiling, 500.0 mg of

Fe(NH4

)2

(SO4

)2•6H2O is added, reducing the Cr2O7

2-

to Cr3+

.

The excess Fe2+ is back titrated, requiring 18.29 mL of 0.00389

M K2Cr2O7 to reach the end point. Determine the average

thickness of the chromium plate given that the density of Cr is

7.20 g/cm3

. Note: thickness = volume /area

 

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