The standardization of same titrant during the determination of BOD5 of water sample was done separately for Day 1 and Day 5. Upon standardization, it turned out that the concentration of the titrant in Day 1 is higher than the concentration of the same batch of titrant in Day 5. How would you explain this discrepancy?

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter3: Statistical Tests With Excel
Section: Chapter Questions
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The standardization of same titrant during the determination of BOD5 of water sample was done separately for Day 1 and Day 5. Upon standardization, it turned out that the concentration of the titrant in Day 1 is higher than the concentration of the same batch of titrant in Day 5. How would you explain this discrepancy?

 
  1. The water used to prepare the Na2S2O3 solution was not boiled resulting to proliferation of bacteria.

     
  2. Too much starch indicator was added in the conical flask.

     
  3. Sulfuric acid was added first before potassium iodide.

     
  4. There were bubbles at the tip of the burette during titration.

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