Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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1. Calculate the standard reaction free energy of the following chemical reaction :
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- Constants I Periodic Table The standard free energy of formation, AG; , of a substance is the free energy change for the formation of one mole of the substance from the component elements in their standard states. These values are applicable at 25°C and are found in thermodynamic tables. Part A Based on the standard free energies of formation, which of the following reactions represent a feasible way to synthesize the product? The value of AG; for a substance gives a measure of the thermodynamic stability with respect to the component elements. Negative values for a formation reaction indicate thermodynamic stability of the product. In other words, the compound formed does not spontaneously decompose back into the component elements. Positive values for a formation reaction indicate thermodynamic instability of the product. Thus, the compound will spontaneously decompose, though the rate may be slow. Drag the appropriate items to their respective bins. Reset Не 2Na(s) + O2(g)→N22O2(s)…arrow_forwardA student determines the value of the equilibrium constant to be 7.49×10-37 for the following reaction. H,S(g) + 2H2O(1)3H2(g) + SO2(g) Based on this value of Kegi AG° for this reaction is expected to be (greater, less) than zero. Calculate the free energy change for the reaction of 2.03 moles of H,S(g) at standard conditions at 298K. AG. rxn kJarrow_forwardThe difference in standard free energy between reactant R and product P is + 7.5 kJ/mol. What’s the ratio of P to R at equilibrium? P to R ratio =arrow_forward
- A student determines the value of the equilibrium constant to be 2.22x10 2 for the following reaction. CH (g) + H,O(g) →3H2(g) + CO(g) Based on this value of Keg AG° for this reaction is expected to be (greater, less) than zero. Calculate the free energy change for the reaction of 2.05 moles of CH,(g) at standard conditions at 298K. AG°. Ixn kJarrow_forward2. Calculate AH for the following reaction at 25.0 °C: 30 Fe₂O4(s) + CO(g) 3FeO(s) + AH (kJ/mol)-1118 -110.5 -272 CO₂(g) -393.5arrow_forward1)State the First Law of Thermodynamics. 2)Fluorine (F2) and iodine (I2) are both Group 17 elements. Explain with reference to intermolecular forces, why fluorine is a gas and iodine is a solid at room temperature. 4)When 30 g of ammonium nitrate, (NH4NO3) was stirred into 10 cm3 of water, the temperature fell from 21 oC to 15 oC. 5)Calculate the total amount of energy (E) released in this experiment. Ignore the heat capacity of ammonium nitrate. Take the specific heat capacity of the water as 4.18 J g-1 ºC-1. Density of water is 1.00 gcm-3. 6)This amount of energy [answer to part (i)] was produced by 30 g of ammonium nitrate. Calculate the energy change per mole of ammonium nitrate. Include the correct sign for…arrow_forward
- Calculate ΔH°, ΔS° and ΔG° for the synthesis of SO3(g) Be sure to use the values provided in this table: Compound ΔHf° (kJ/mol) S° (J/Kmol) SO2(g) -253 231 SO3(g) -345 219 O2(g) 0 205 a) give the balance equation for the synthesis of SO3(g) from SO2(g) and O2(g) b) What is ΔH° for this process? c) What is ΔS° for this process? d) What is ΔG° for this process?arrow_forwardKa = 4.5 × 10-4 at 25°C of nitrous acid (HNO2). What is the ΔG value at equilibrium?arrow_forwardAcetylene gas, C2H21g2, is used in welding. What is the maximum amount of useful work that can be accomplished under standard conditions by this reaction?arrow_forward
- A student determines the value of the equilibrium constant to be 1.39x1025 for the following reaction. 2502(g) + O2(8)2S03(g) Based on this value of Keg: AG° for this reaction is expected to be (greater,less) than zero. Calculate the free energy change for the reaction of 1.84 moles of SO2(g) at standard conditions at 298K. AG° rxn kJarrow_forwardHemoglobin, abbreviated Hgb, reacts with a certain oxide, XO, and oxygen gas, 02. Consider the following reactions and approximate standard free energy changes: ΔG° = -70.00 kJ AG° = -93.4 kJ Hgb + 02 = Hgb02 Hgb + XO = HgbXO Using these data, estimate the equilibrium constant value at 25 °C for the following reaction: Hgbo2 + XO = HgbXO + 02 Please make sure to use 4 sig. figs throughout your calculations. Answer: -23.40 The correct answer is: 12634.20arrow_forwardGiven the following thermodynamic data: CO2(g) + 2NH3(g) → CO(NH2)2(s) + H2O(l) ΔH°298 =-133.3 kJ ΔG°298 =-6.97 kJ ΔH°f (kJ/mol) -393.5 -46.11 -285.8 S° (J/mol K) 213.6 192.3 104.6 69.91 a) Determine ΔH⁰f for CO(NH2)2(s) b) Determine K for the reaction at 298 K c) Determine ΔS⁰ for the reaction in units of J/K d) Determine ΔG if the pressure of CO2 is 0.450 bar and the pressure of NH3 is 0.650 bar e) Determine K for the reaction at 250 Karrow_forward
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