Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The reaction that was on the screen when you started and its derivative demonstrate that the reaction enthalpy, ΔH, changes sign when a process is reversed.

Consider the reaction

H2O(l)→H2O(g), ΔH =44.0kJ

What will ΔH be for the reaction if it is reversed?

N2 (g) + O2 (g) → 2NO (g) AH = 180.5 kJ
AH is an Extensive Property
(g)
NO (g) AH = 90.25 kJ
AH Changes sign when a
process is reversed
2NO(g) → N2(g) + O2 (g) AH
- 180.5 kJ
글N2 (g) + 글02 (g) →
NQ (g) AH = 90.25 kJ
Hess's Law of Constant
Heat Summation.
NO (g) + 02 (g) → NO2 (g) AH = - 57.05 kJ
N2 (g) + O2 (g) → NO2 (g) AH = 33.20 kJ
When two reactions are added together,
the individual reaction enthalpies are
summed. Notice that equal quantities of
the same species, on both sides of the
reaction arrow, cancel.
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Transcribed Image Text:N2 (g) + O2 (g) → 2NO (g) AH = 180.5 kJ AH is an Extensive Property (g) NO (g) AH = 90.25 kJ AH Changes sign when a process is reversed 2NO(g) → N2(g) + O2 (g) AH - 180.5 kJ 글N2 (g) + 글02 (g) → NQ (g) AH = 90.25 kJ Hess's Law of Constant Heat Summation. NO (g) + 02 (g) → NO2 (g) AH = - 57.05 kJ N2 (g) + O2 (g) → NO2 (g) AH = 33.20 kJ When two reactions are added together, the individual reaction enthalpies are summed. Notice that equal quantities of the same species, on both sides of the reaction arrow, cancel.
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