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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The rate of attack on [Co(H 2 O) 6 ]^ 3+ by an entering group Y is nearly independent of Y, with the exception of the rapid reaction with OH^ - Explain this anomaly. What is the implication of your explanation for the behavior of a complex lacking Brønsted acidity on the ligands?
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- Describe the difference between a labile and an inert ligand on a metal complex.arrow_forwardName the following complex ions. formula name 3+ Ag(NH, ¬4+ Mn (н, о),arrow_forward[Cd(CN)4] complex K₁=6.03 × 10¹8 at 25 °C. x Suppose equal volumes of 0.0086M Cd (NO3), solution and 0.18M KCN solution are mixed. Calculate the equilibrium molarity of aqueous Cd²+ ion. For the aqueous Round your answer to 2 significant digits.arrow_forward
- 1. What is the balanced net ionic equation for the equilibrium involving complex ions, CoCL42- and [Co(H2O)6]2+. 2. When heating the mixture the color was blue and when cooled it was pink. Based on this, is the forward reaction endothermic or exothermic and why? What is the balanced net ionic equation when heat is included? 3. How could an alcohol solution of CoCL2 beused to predict rain?arrow_forwardCHEMWORK To make 1.50 L of 0.100 MNaCl from a 3.00 M stock solution, you would need to take mL of the stock solution and add mL of water.arrow_forward14. The complex ion [Ni(TAP)(CN)]+ has a distorted trigonal bipyramidal structure, the complex ion has a coordination number… A. 4B. 6C. 5D. 7arrow_forward
- In the following chemical reaction what is the concentrations of [H3O+] in a solution that is 0.00045 M [Al(H2O)6]3+. Assume that the [Al(H2O)6]3+ dissociates 100% completely and assume 1 Liter of solution. [Al(H2O)6]3+ + 3H2O ↔ [Al(H2O)3(OH)3]2+ + 3H3O+arrow_forwardCOBALT COMPLEX: [CoCl4]2-(aq) + 6H2O(l) « [Co(H2O)6]2+(aq) + 4Cl-(aq) + Heat Blue Pink STEPS #- Solutions Observations 1-DISSOLVE COBALT COMPLEX PINK SOLUTION 2-SOLUTION PLUS HCl BLUE SOLUTION 3-ADD WATER PINK SOLUTION 4-HEAT SOLUTION BLUE SOLUTION According to the equilibrium equation, which ion(s) do you have when the solution dissolved? Explain how you know the identity of the ion(s) present. 2. Explain what happened when the HCl was added to the solution. 3. Explain what happened when the H2O was added to the solution. 4. Explain what happened when the solution was heated. Was the reaction exothermic or endothermic?arrow_forwardIs the reaction [Co(NH 3 ) 6 ]^ 3+ +[Cr(H 2 O) 6 ]^ 2+ likely to proceed by an inner-sphere or outer sphere mechanism? Explain your answer.arrow_forward
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