The occupation probability of state / with an energy & is given by: exp(-ɛ¡/kµT) q p(ε₁) = where k is the Boltzmann constant, q the partition function, and T the temperature. For a system with three states & (ground state), &₁, and &2, the respective occupation probabilities are po = 0.9, p₁ = 0.09 and p2 = 0.01 at 298 K. (a) Write down the expression for the partition function q for the system assuming the ground state energy &o= 0; (b) Determine the value of the partition function q using the given occupation probability for the ground state.

The occupation probability of state / with an energy & is given by: exp(-ɛ¡/kµT) q p(ε₁) = where k is the Boltzmann constant, q the partition function, and T the temperature. For a system with three states & (ground state), &₁, and &2, the respective occupation probabilities are po = 0.9, p₁ = 0.09 and p2 = 0.01 at 298 K. (a) Write down the expression for the partition function q for the system assuming the ground state energy &o= 0; (b) Determine the value of the partition function q using the given occupation probability for the ground state.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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