
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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![The nucleophilic reaction between phenyl a-disulfone and hydrazine
occurs according to the following reaction:
PhSO2SO,Ph+NH,PhSO,NHNH,+PhSOH.
In experiments where [disulfoneo]= 3.15x10-5 M and excess of hydrazine,
the reaction follows first-order kinetics in the disulfone. From the
following values:
[N2H4](10-²M) 0.5
Vo (Ms ¹)
1.0
1.6
0.085 0.176 0.300
2.0
3.0
4.0
0.410 0.670 0.950
Find the total reaction order and the value of the real reaction constant:
Total reaction order =
Real reaction constant =
x10-6](https://content.bartleby.com/qna-images/question/e2f0b0d4-36ab-47d6-988b-5e7e27f61db9/79a61d4a-bed0-4329-b1d5-f227fd21deee/91eyq5z_thumbnail.png)
Transcribed Image Text:The nucleophilic reaction between phenyl a-disulfone and hydrazine
occurs according to the following reaction:
PhSO2SO,Ph+NH,PhSO,NHNH,+PhSOH.
In experiments where [disulfoneo]= 3.15x10-5 M and excess of hydrazine,
the reaction follows first-order kinetics in the disulfone. From the
following values:
[N2H4](10-²M) 0.5
Vo (Ms ¹)
1.0
1.6
0.085 0.176 0.300
2.0
3.0
4.0
0.410 0.670 0.950
Find the total reaction order and the value of the real reaction constant:
Total reaction order =
Real reaction constant =
x10-6
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