Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A 56.2 g sample of aluminum, which has a specific heat capacity of 0.897 J-g¹C¹, is put into a calorimeter (see sketch at right) that contains 250.0 g of water. The temperature of the water starts off at 24.0 °C. When the temperature of the water stops changing it's 26.9 °C. The pressure remains constant at 1 atm. Calculate the initial temperature of the aluminum sample. Be sure your answer is rounded to the correct number of significant digits. °C X Ś thermometer- insulated. container water sample a calorimeterarrow_forwardMeasurements show that the energy of a mixture of gaseous reactants increases by 270.kJ during a certain chemical reaction, which is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that −195.kJ of work is done on the mixture during the reaction. Calculate the change in enthalpy of the gas mixture during the reaction in kJ. Is the reaction exothermic or endothermic.arrow_forwardMeasurements show that the energy of a mixture of gaseous reactants decreases by 373. kJ during a certain chemical reaction, which is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that 136. kJ of work is done on the mixture during the reaction. Calculate the change in enthalpy of the gas mixture during the reaction. Round your answer to 3 x10 significant digits. exothermic Is the reaction exothermic or endothermic? endothermicarrow_forward
- A student runs two experiments with a constant-volume "bomb" calorimeter containing 1400. g of water (see sketch at right). First, a 5.000 g tablet of benzoic acid (CH-CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 21.00 °C to 42.00 °C over a time of 8.5 minutes. Next, 5.190 g of ethylene (C₂H4) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 21.00 °C to 63.35 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. exothermic C₂H₂(g) + 30₂(g) → 2CO₂(g) + 2H₂O(g) Be…arrow_forwardWhen 6.10 g of urea,(NH2)2CO (g), burns to produce CO2 (g), N2 (g) and H2O (l) 67.8 kJ of heat energy are released in a bomb calorimeter. What is the energy released in the burning of one mole of urea? Using this, what is the enthalpy of formation of urea?arrow_forwardA sample of iron, which has a specific heat capacity of 0.449 J-g¹C¹, is put into a calorimeter (see sketch at right) that contains 150.0 g of water. The iron sample starts off at 85.1 °C and the temperature of the water starts off at 22.0 °C. When the temperature of the water stops changing it's 24.3 °C. The pressure remains constant at 1 atm. Calculate the mass of the iron sample. Be sure your answer is rounded to 2 significant digits. 08 X S thermometer. insulated container water- sample a calorimeter 區 dearrow_forward
- A student runs two experiments with a constant-volume "bomb" calorimeter containing 1300. g of water (see sketch at right). First, a 5.000 g tablet of benzoic acid (CH-CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 22.00 °C to 42.76 °C over a time of 9.6 minutes. Next, 5.990 g of ethane (C₂H) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 22.00 °C to 71.14 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy ΔΗ per mole of C₂H6.…arrow_forward5.00 × 10−2 mol KOH and an excess of hydrochloric acid are combined in 100.0 mL of water initially at 25.0 °C, leading to a final measured temperature of 31.1 °C. (a) What is the heat flow for the water in the calorimeter, qH2O, in Joules? (b) Assuming the calorimeter constant Ccal = 50.0 J °C , what is the heat flow for the calorimeter, qcal, in Joules? (c) What is the amount of heat given off by the reaction, qrxn, in Joules? (d) What is the molar enthalpy of the neutralization reaction (shown below) as measured in the calorimeter, ∆H◦ rxn in kilojoules per mole? H3O + (aq) + OH– (aq) → 2H2O (l)arrow_forwardA student runs two experiments with a constant-volume "bomb" calorimeter containing 1200. g of water (see sketch at right). First, a 7.500 g tablet of benzoic acid (CH₂CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 18.00 °C to 51.74 °C over a time of 14.9 minutes. Next, 4.510 g of ethane (C₂H₂) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 18.00 °C to 53.35 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy ΔΗ per mole of C₂H6.…arrow_forward
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