Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. In an experiment, a 0.7090 g sample of adipic acid (C6H1004) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1.201×10° g of water. During the combustion the temperature increases from 22.33 to 24.58 °C. The heat capacity of water is 4.184 J gloc!. The heat capacity of the calorimeter was determined in a previous experiment to be 799.0 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of adipic acid based on these data. CGH1004(s) + (13/2) O2(g) → 5 H,O(1) + 6 CO2(g) + Energy Molar Heat of Combustion = kJ/molarrow_forwardA bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. In an experiment, a 1.4710 g sample of maleic acid (C4H4O4) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1159 g of water. During the combustion the temperature increases from 22.46 to 25.59 °C. The heat capacity of the calorimeter, not including the surrounding water, was determined in a previous experiment to be 852.2 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of maleic acid based on these data. Assuming that no energy is lost to the surroundings, what is the molar heat of combustion of maleic acid, based on these data? (in kJ/mol). C4H4O4(s) + 3O2(g) → 2 H2O(l) + 4 CO2(g) + Energyarrow_forwardThe combustion of titanium with oxygen produces titanium(IV) oxide: Ti(s)+O2(g)→TiO2(g) When 2.060 g of titanium is combusted in a calorimeter, the temperature of the calorimeter increases from 25.00°C to 91.60 °C. If the heat capacity of the calorimeter is 9.84 kJ/°C, what is the heat associated with the combustion of one mole of Ti in this calorimeter?arrow_forward
- Ethylene glycol, HOCH2CH2OH, is used as antifreeze. It is produced from ethylene oxide, C2H4O, by the following reaction.C2H4O(g) + H2O(l) ? HOCH2CH2OH(l)Use Hess's law to obtain the enthalpy change for this reaction from the following enthalpy changes.2 C2H4O(g) + 5 O2(g) ? 4 CO2(g) + 4 H2O(l) ?H = -2612.2 kJHOCH2CH2OH(l) + 5/2 O2(g) ? 2 CO2(g) + 3 H2O(l) ?H = -1189.8 kJarrow_forwardA 2.30 g sample of ethanol, CH3CH2OH, is combusted in a bomb calorimeter. The temperature of the calorimeter increases by 4.89 K. If the heat capacity of the bomb is 663 J/K and it contains 2.57 kg of water, what is the enthalpy change per mole of ethanol combusted? The specific heat capacity of water is 4.18 J/g×K and the molar mass of ethanol is 46.07 g/mol.arrow_forwardA scientist measures the standard enthalpy change for the following reaction to be -104.0 kJ : Cog) + Cl2(g)–→COCl2(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of CO(g) is kJ/mol.arrow_forward
- When a 4.31 g sample of liquid octane (C8H18) is burned in a bomb calorimeter, the temperature of the calorimeter rises by 27.3 °C. The heat capacity of the calorimeter, measured in a separate experiment, is 6.2 kJ/•C. The calorimeter also contains 3.00 kg of water, specific heat capacity of 4.18 J/g°C. Determine the heat of combustion of octane in units of kJ/mol octane. Enter your answer numerically and in terms of kJ/mol.arrow_forwardMeasurements show that the energy of a mixture of gaseous reactants decreases by 373. kJ during a certain chemical reaction, which is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that 136. kJ of work is done on the mixture during the reaction. Calculate the change in enthalpy of the gas mixture during the reaction. Round your answer to 3 x10 significant digits. exothermic Is the reaction exothermic or endothermic? endothermicarrow_forwardThe flame in a torch used to cut metal is produced by burning acetylene (C2H2)(26.04 g/mol) in pure oxygen. Assuming the combustion of 1 mole of acetylene releases 1251 kJ of heat, what mass of acetylene is needed to cut through a piece of steel if the process requires 22.5 × 104 kJ of heat? 2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g) ΔH = –2502 kJarrow_forward
- A 56.5 g sample of iron is put into a calorimeter (see sketch at right) that contains 300.0 g of water. The iron sample starts off at 86.7 °C and the temperature of the water starts off at 21.0 °C. When the temperature of the water stops changing it's 22.8 °C. The pressure remains constant at 1 atm. Calculate the specific heat capacity of iron according to this experiment. Be sure your answer is rounded to 2 significant digits. J 0₂-C x10 x thermometer insulated container water sample a calorimeterarrow_forwardA 56.1 g sample of polystyrene, which has a specific heat capacity of 1.880 J-g °C-1 is put into a calorimeter (see sketch at right) that contains 250.0 g of water. The temperature of the water starts off at 24.0 °C. When the temperature of the water stops changing it's 29.8 °C. The pressure remains constant at 1 atm. Calculate the initial temperature of the polystyrene sample. Be sure your answer is rounded to the correct number of significant digits. °C thermometer. insulated container water sample. a calorimeter 區 OU Ararrow_forwardA bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. In an experiment, a 0.3215 g sample of phenanthrene (C14H10) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1.162×10 g of water. During the combustion the temperature increases from 25.15 to 27.48 °C. The heat capacity of water is 4.184 J glc-!. The heat capacity of the calorimeter was determined in a previous experiment to be 769.3 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of phenanthrene based on these data. C14H10(s) + (33/2) O,(g) – → 5 H,O(1) + 14 CO2(g) + Energy Molar Heat of Combustion = kJ/molarrow_forward
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