The following are some normal modes of vibration for several molecules. In each case: • Determine the point group for the molecule • Determine how the vibration transforms under each symmetry operation of the point and assign the appropriate irreducible representation • State whether the vibration is IR active and'or Raman active (benzene): CC strotch C=C stretch "Breathing CC twist CC twist b. t. "Flexing Asymmetric CH and C-Cl stretches Asymmetric C-H and C-Ci stretches 9. Symmetric C-H and C-Ci stretches Symmetric C-H and C-CI stretches Asymmetric C-H stretches d. h. 0-

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Chapter1: Chemical Foundations
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The following are some normal modes of vibration for several molecules. In each case:
Determine the point group for the molecule
Determine how the vibration transforms under each symmetry operation of the point and assign the
appropriate irreducible representation
State whether the vibration is IR active and/or Raman active
Cote
(benzene):
C=C stretch
c=C stretch
a.
e.
"Breathing"
CC twist
C=C twist
b.
"Flexing"
Asymmetric C-H
and C-Ci stretches
Asymmetric C-H
and C-Ci stretches
C.
g.
Symmetric C-H
and C-Cl stretches
Symmetric C-H
and C-CI stretches
Asymmetric
C-H stretches
d.
h.
k.
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Transcribed Image Text:AutoSave O ff 331SYL22 - - O Search (Alt+Q) Yuleymi Gondola Protected View · Saved to this PC File Design References Mailings Review View Help P Comments v A Share Home Insert Draw Layout The following are some normal modes of vibration for several molecules. In each case: Determine the point group for the molecule Determine how the vibration transforms under each symmetry operation of the point and assign the appropriate irreducible representation State whether the vibration is IR active and/or Raman active Cote (benzene): C=C stretch c=C stretch a. e. "Breathing" CC twist C=C twist b. "Flexing" Asymmetric C-H and C-Ci stretches Asymmetric C-H and C-Ci stretches C. g. Symmetric C-H and C-Cl stretches Symmetric C-H and C-CI stretches Asymmetric C-H stretches d. h. k. Page 6 of 6 3011 words Text Predictions: On O Focus 100% 12:01 PM O Type here to search 12% 4 71°F * 4) ENG 3/23/2022 19 近
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