Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- The equilibrium constant, Kp, for the reaction PCl5 (g) > PCl3 + Cl2 is 1.26 at 250°C. The reaction is started with PCl5, PCl3, and Cl2 at 0.01, 0.2 and 0.5 atm at 250°C. When will the reaction come to equilibrium?arrow_forwardThe equilibrium constant (Kc ) for the reaction: PCl3 + Cl2 <=> PCl5 equals 51 at 235°C. If 0.648 mol of phosphorus trichloride and 0.748 mol chlorine (Cl2) are added to a 9.00 L reaction vessel, what is the amount of moles of Cl2 at equilibrium in the mixture at 235°C?arrow_forwardConsider the equilibrium system described by the chemical reaction below. If the partial pressures at equilibrium of NO, Cl2, and NOCI are 0.095 atm, 0.171 atm, and 0.28 atm, respectively, in a reaction vessel of 7.00 L at 500 K, what is the value of Kp for this reaction? 2 NO(g) + Cl2(g) = 2 NOCI(g)arrow_forward
- A chemical engineer is studying the following reaction: HCH;CO,(aq)+CH;NH,(aq) → CH;CO,(aq)+CH,NH,(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.73. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel HCH;CO, 1.18 M f increase I decrease (no change) CH, NH, 0.97 M f increase OI decrease O (no change) A CH,CO, 0.39 M f increase O I decrease (no change) + CH,NH, 0.39 M f increase Ot decrease (no change) HCH,CO, 1.15 M f increase OI decrease O (no change) CH,NH, 0.88 M t increase I decrease (no change) В CH,CO, 0.86 M f increase OI decrease (no change) CH,NH,…arrow_forwardA chemical engineer is studying the following reaction: HCH;CO,(aq)+CH,NH,(aq) → CH;CO,(aq)+CH,NH,(2q) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.6. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction compound expected change in cor concentration concentration vessel HCH,CO, 0.96 M O T increase OI decrease O (no change) CH, NH, 0.88 M O f increase OI decrease O (no change) A CH,Co, 0.54 M O f increase OI decrease O (no change) CH,NH, 0.45 M O f increase OI decrease O (no change) HCH, CO, 0.88 M f increase OI decrease O (no change) CH,NH, 0.77 M O f increase OI decrease O (no change) B CH, Co, 1.09 M O increase OI…arrow_forwardA chem ngineer is studying the following reaction: 4 HCl(g)+O,(g) – 2 H,0(g)+2Cl,(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.0040. The engineer charges ("fillsf) four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. He then measures the co mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel HCl 8.71 atm Ot increase O! decrease O (no change) 02 8.13 atm O t increase OI decrease O (no change) H,0 3.63 atm Ot increase OI decrease (no change) I decrease (no change) Cl, 1.91 atm ease I decrease (no change) 7,61 atm t increase HCI I decrease O (no change) 7,86 atm O f increase 0, I decrease O (no change) 4.18 atm t increase H,0 I decrease (no change) t increase 2.46 atm Cl, I decrease O (no…arrow_forward
- A chemical engineer is studying the following reaction: H₂(g) + Cl₂(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.83. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A C compound H₂ Cl₂ HCI H₂ CL₂ HCI H₂ CL₂ HCI pressure 4.00 atm 1.97 atm 3.36 atm 4.27 atm 2.82 m 3.84 atm 1.81 atm 3.69 atm expected change in pressure 1 increase O decrease decrease Of increase Of increase Ⓒ↓ decrease Of increase O decrease decrease O1 increase Ot increase O decrease Of increase O decrease Of increase O decrease decrease Of increase O (no change) (no change) O(no change) (no change) (no change) (no change) (no change) (no…arrow_forwardPhosphorus pentachloride decomposes according to the chemical equation PCI, (g) = PCI, (g) + Cl, (g) K. = 1.80 at 250 °C A 0.3668 mol sample of PCI, (g) is injected into an empty 4.30 L reaction vessel held at 250 °C. Calculate the concentrations of PCl, (g) and PCI, (g) at equilibrium. [PCl,] = M [PCI,] = Marrow_forward
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