
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
thumb_up100%
![The data of the initial rate experiment of the following reaction are given below. The rate law expression of the reaction is Rate = \( k \ [ \text{S}_2\text{O}_8^{2-} ]^x [ \text{I}^- ]^y \). Determine the rate constant \( k \) with 3 significant figures (key in only your value; no units are needed). Note that your \( k \) value should be reported based on second (the time units here). Do not convert second to other time units.
\[ \text{S}_2\text{O}_8^{2-} (\text{aq}) + 3 \, \text{I}^- (\text{aq}) \rightarrow 2 \, \text{SO}_4^{2-} (\text{aq}) + \text{I}_3^- (\text{aq}) \]
\[
\begin{array}{|c|c|c|c|}
\hline
\text{Trial} & [\text{S}_2\text{O}_8]_{0} \, (\text{M}) & [\text{I}^-]_{0} \, (\text{M}) & \text{Initial rate} \, (\text{M/sec}) \\
\hline
1 & 0.800 & 0.140 & 0.0288 \\
2 & 2.400 & 0.140 & 0.2592 \\
3 & 0.800 & 0.280 & 0.0288 \\
\hline
\end{array}
\]
**Note that Trial 1 and Trial 3 have the same initial rate.**](https://content.bartleby.com/qna-images/question/18593a3a-b463-4aeb-a821-a472ffee6b36/37cfb881-4ebc-42d2-8ea1-532f79627f10/5jrmox4_thumbnail.png)
Transcribed Image Text:The data of the initial rate experiment of the following reaction are given below. The rate law expression of the reaction is Rate = \( k \ [ \text{S}_2\text{O}_8^{2-} ]^x [ \text{I}^- ]^y \). Determine the rate constant \( k \) with 3 significant figures (key in only your value; no units are needed). Note that your \( k \) value should be reported based on second (the time units here). Do not convert second to other time units.
\[ \text{S}_2\text{O}_8^{2-} (\text{aq}) + 3 \, \text{I}^- (\text{aq}) \rightarrow 2 \, \text{SO}_4^{2-} (\text{aq}) + \text{I}_3^- (\text{aq}) \]
\[
\begin{array}{|c|c|c|c|}
\hline
\text{Trial} & [\text{S}_2\text{O}_8]_{0} \, (\text{M}) & [\text{I}^-]_{0} \, (\text{M}) & \text{Initial rate} \, (\text{M/sec}) \\
\hline
1 & 0.800 & 0.140 & 0.0288 \\
2 & 2.400 & 0.140 & 0.2592 \\
3 & 0.800 & 0.280 & 0.0288 \\
\hline
\end{array}
\]
**Note that Trial 1 and Trial 3 have the same initial rate.**
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by stepSolved in 4 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 4. Predict the products of the following irreversible additions to carboxylic acid derivatives. CI excess MeMgBr excess NaBH4 CI excess MeLi excess LiAlH4 CI CI NMe2 excess MeMgBr NMe2 excess NaBH4 NMe2 excess MeLi NMe2 excess LiAlH4arrow_forwardThe thermal decomposition of PH3 is a first order process: 4 PH3(g) → P4(g) + 6 H2(g) If the value for the rate constant, k equals 2.00 x 10-2/sec, how long (sec) would it takes for 85% of the PH3 to decompose? Express the answer to 3 sig. figs. ln[A]t = -kt + ln[A]oarrow_forward7arrow_forward
- 5. You studied the chemical reaction, 2NO2(g) → 2NO(g) + O2(g), at 25°C by monitoring the concentration of NO2(g) as a function of time and constructed the following graph. y= 0.5408x + 125.0 R2=0.998 Time (s) What is the rate constant for this reaction at 25°C? Include the proper units. (W/T) [(3)ONI/Tarrow_forwardA value of k is found from the rate equation Rate = k[A]m[B]n. If m=1 and n=4 and -1 the unit for the initial rate is M/h. The unit of k is found to be MX h-¹ (M to the power of x h to the power of minus 1). What is the value of x?arrow_forwardFor the reaction: NO (g) + O3 (g) ---> NO2 (g) + O2 (g) the value of A= 8.7 x 1012 s-1 and Ea = 63 kJ/mol. What is the value of the rate constant k for the reaction at 75oC? Enter your answer in units of s-1 to 2 significant figures. Enter your answer in the format: a.b x10^m, where a.b and m are the appropriate numbers based on your calculation.arrow_forward
- Determine the average rate of change of B from t O s to Time (s) Concentration of A (M) t = 282 s. 0.740 141 0.465 A - → 2B 282 0.190 rateB M/sarrow_forwardConsider a reaction: A+ B → C and the rate law expression: Rate = k [A]M[B]^ %3D In the rate law expression above, what do 'm' and 'n' determine? order of reaction concentration of A and B they have no significance I have no ideaarrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY