The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4025 g sample of CaCO3 was transferred into a 250 mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3-NH4Cl buffer containing a small amount of Mg2+EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA requiring 42.36 mL to reach the end point. Report the molar concentration of the titrant.

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