The chemical environment of carbons can be deduced form their chemical shifts. Deduce the relative chemical shifts of the carbons at the labeled positions. (Carbons that are highly shielded have low delta, chemical shift, values.) 1) b The carbon with the smallest delta value (the most shielded) is The carbon with the largest delta value (the most deshielded) is 2) H. но. H 9 HO. (+)-2-Deoxyuridine The carbon with the smallest delta value (the most shielded) is The carbon with the largest delta value (the most deshielded) is

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter13: Structure Determination: Nuclear Magnetic Resonance Spectroscopy
Section13.12: Dept 13c Nmr Spectroscopy
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The chemical environment of carbons can be deduced form their chemical
shifts. Deduce the relative chemical shifts of the carbons at the labeled
positions. (Carbons that are highly shielded have low delta, chemical shift,
values.)
1)
b
The carbon with the smallest delta value (the most shielded) is
The carbon with the largest delta value (the most deshielded) is
2)
NH.
но.
H.
b
но,
(+)-2-Deoxyuridine
The carbon with the smallest delta value (the most shielded) is
The carbon with the largest delta value (the most deshielded) is
Transcribed Image Text:The chemical environment of carbons can be deduced form their chemical shifts. Deduce the relative chemical shifts of the carbons at the labeled positions. (Carbons that are highly shielded have low delta, chemical shift, values.) 1) b The carbon with the smallest delta value (the most shielded) is The carbon with the largest delta value (the most deshielded) is 2) NH. но. H. b но, (+)-2-Deoxyuridine The carbon with the smallest delta value (the most shielded) is The carbon with the largest delta value (the most deshielded) is
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1.

The carbon with smallest detlta value(the most shielded) is=b

The carbon with largest detlta value(the most dishielded) is=c

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