The absorbance of compound A was measured in a 1.00 cm cuvette at 238 nm. A 3.96 x 10* M solution of compound A exhibited an absorbance of 0.624. A blank solution containing only the solvent had an absorbance of 0.029 at the same wavelength. (a) (i) Calculate the molar absorptivity of compound A in m' mole". (i) The absorbance of an unknown solution of Compound A in the same solvent and cuvette was 0.375 at 238 nm. Find the concentration of A in the unknown. (i) A concentrated solution of Compound A in the same solvent was diluted from an initial volume of 2.00ml to a final volume of 25 ml and then had an absorbance of 0.733 under the same conditions. What is the concentration of A in the concentrated solution?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.32QAP
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2.
Answer ALL parts.
(a)
The absorbance of compound A was measured in a 1.00 cm cuvette at 238 nm.
A 3.96 x 10 M solution of compound A exhibited an absorbance of 0.624. A
blank solution containing only the solvent had an absorbance of 0.029 at the
same wavelength.
Calculate the molar absorptivity of compoundA in m' mole".
(i)
The absorbance of an unknown solution of Compound A in the same
solvent and cuvette was 0.375 at 238 nm. Find the concentration of A in
the unknown.
(iii) A concentrated solution of Compound A in the same solvent was diluted
from an initial volume of 2.00ml to a final volume of 25 ml and then had
an absorbance of 0.733 under the same conditions. What is the
concentration of A in the concentrated solution?
(iv) What type of cuvette was used in the above analysis? Justify your
answer.
(b)
Name ONE advantage and ONE disadvantage of a linear photodiode array
detector compared to a traditional photomultiplier based spectrometer.
(c)
Why is an FTIR spectrum digital in nature?
(d)
Name an optical material typically used in FTIR.
Transcribed Image Text:2. Answer ALL parts. (a) The absorbance of compound A was measured in a 1.00 cm cuvette at 238 nm. A 3.96 x 10 M solution of compound A exhibited an absorbance of 0.624. A blank solution containing only the solvent had an absorbance of 0.029 at the same wavelength. Calculate the molar absorptivity of compoundA in m' mole". (i) The absorbance of an unknown solution of Compound A in the same solvent and cuvette was 0.375 at 238 nm. Find the concentration of A in the unknown. (iii) A concentrated solution of Compound A in the same solvent was diluted from an initial volume of 2.00ml to a final volume of 25 ml and then had an absorbance of 0.733 under the same conditions. What is the concentration of A in the concentrated solution? (iv) What type of cuvette was used in the above analysis? Justify your answer. (b) Name ONE advantage and ONE disadvantage of a linear photodiode array detector compared to a traditional photomultiplier based spectrometer. (c) Why is an FTIR spectrum digital in nature? (d) Name an optical material typically used in FTIR.
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