Term Symbol Assignment: For your assigned set: 1. Draw all possible microstates. 2. Sort the microstates into an M₁/Ms matrix 3. Assign term symbols to all the microstates 4. Assign J values to each term symbol 5. Use Hund's rule to find your term symbol with the lowest energy. Sets: USE LAST DIGIT OF YOUR ID NUMBER 2 electrons in p orbitals: one in 2p, one in 3p (ID: 0,2,4) 2 electrons in 3d orbitals (ID:1,3,5,6) 2 electrons: one in a 4s, one in a 3d (ID: 7,8,9)
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- Part A What is the probability that this molecule will be in the lowest-energy state? Express your answer to three significant figures. ? Pi = Submit Previous Answers Request Answer X Incorrect; Try Again; 5 attempts remaining Part B What is the probability that it will be in the highest-energy state? Express your answer to three significant figures.For the p3 configuration, answer the questions below: 1-Calculate the number of microstates. 2-Show the arrangement of electrons. 3-Determine the terms and identify the ground term.Explain how you calculate the values for the “F” rowof the ICF table.
- 3. a) Sort the following free atom tem symbols into ascending order of energy: 'F, $F, °S, °P, ?D, ?S, G, 'S b) Predict the microstate table for the s'd' configuration. Assign the ground state term symbol.11. What is the wavenumber of light with a frequency of a. 5.28 x 1012 sec-1? b. 3.17 x 1013 sec-1? What is the wavelength of light with energy ofa. 4.29 x 10-24 J? b. 9.03 x 10-22 J?1. Fill in the microstate table for a d² electronic configuration. These are for the free ion (therefore all energy levels are degenerate). Follow the Pauli exclusion principle. Sketch the energy levels for various microstates to convince yourself that they are allowed. Superscript + means the electron is spin up. See example below for Ms = 0 and M₁ = = +4. ML +4 ML +3 ML +2 ML +1 ML 0 ML-1 ML-2 ML-3 ML-4 Ms -1 Ms 0 (+2+, +2.) Ms +1
- The ml and ms values for the 1st electron of the following microstate, (0*, 0*) are respectively.04. Using the particle in a box model, the energy of the highest occupied energy level (HOMO) for a linear conjugated rocarbon of length 13.5 angstroms and containing 10 n-electrons is: 32x10-¹7 J B) 5.68x10-10 J C) 4.52x10-J D) 7.68x10-¹9 J E) 1.45×10 J F) 8.26×10-¹1-A:-Calculate the energy and wave-length of the photon absorbed when a "Hg"Cl molecule (r. 2.23°A) makes the rotational transition J-0-J-1 and J-1->J=2. B:- In what region of the electromagnetic spectrum are these lines found? 2-Suppose that the equilibrium separation in the '11"CI molecules is the same and equal to 1.27°A. Compute for each molecule A:-The constant 13. B:- The energy of the first two excited rotationa levels. C:-The frequencies and wave length corresponding to the transition J-0-J-1 and J-1-J-2.
- Enumerate the microstates of p3 and its possible electron configurations. Determine the MS and ML values for each microstate.Q1. The classical frequency of vibration (V.) of AB molecule is 4271.8 cm¹ and experimental dissociation energy (D₂) is 5.56 eV. What is the vibrational quantum number (v) at which experimental dissociation occurs? A) 8 B) 10 C) 7 D) 6 E) 9 F) 5 Q2. If a photon of energy 4.9x10-19 Jejects an electron from a metal having a workfunction energy of 2.483 eV, the velocity of the emitted electron is: A) 4.5x10³ m/s B) 1.5x10³ m/s C) 3.2x10³ m/s D) 5.5x10 m/s E) 1.5x10 m/s F) 4.5×10³ m/s Q3. The velocity of an electron having a wavelength of 800 nm is: B) 2.06x10³ m/s A) 1.03x10² m/s C) 9.09×10² m/s E) 7.40x10² m/s F) 4.5x10 m/s D) 3.05x10³ m/s highest occupied energy level (HOMO) for a linear conjugatedA point charge q with a charge of 7.3µC is held at the origin. A second point charge 92 with a charge of -1.2µC is held 4.5cm away. Let the potential energy be zero at an infinite separation between the two charges. What is the electric potential energy stored in this configuration? (Include the appropriate SI Unit) PE