Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carboc…
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond t…
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthes…
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Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
Question

Show the reagents and process of the synthesis.

Synthesize From
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Transcribed Image Text:Synthesize From
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Step 1

The acidic proton in the ketone substrate can be abstracted by the base in order to generate enolate. The nucleophilic carbon than attacks the deficient carbon center in ethyl chloride to generate a carbon-carbon bond. This is followed by Clemmenson reduction in which aldehyde (or ketone) is reduced to alkane in the presence of Zine Amalgam and concentrated HCl.

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