Suppose we have a molecule in C2v . Is an A2 → B2 dipole transition allowed? If so, with what polarization? Refer to the character table below to guide your thinking. 1. Yes, with x polarization. 2. Yes, with y polarization. 3. No, because C2v molecules are nonpolar. 4. No, because there is no polarization with the right symmetry. 5. It is allowed, but only in Raman processes with xz polarizati

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter31: Immunochemistry
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Suppose we have a molecule in C2v . Is an A2 → B2 dipole transition allowed? If so, with what polarization? Refer to the character table below to guide your thinking.

1. Yes, with x polarization.
2. Yes, with y polarization.
3. No, because C2v molecules are nonpolar.
4. No, because there is no polarization with the right symmetry.
5. It is allowed, but only in Raman processes with xz polarization.

 

C2v | E C2
A1
A2
B1
h = 4
1
1
1 z, x², y², z²
1
1 -1
-1
ху
1 -1
B2
-1
х, XZ
1 -1 -1
1
y, yz
Transcribed Image Text:C2v | E C2 A1 A2 B1 h = 4 1 1 1 z, x², y², z² 1 1 -1 -1 ху 1 -1 B2 -1 х, XZ 1 -1 -1 1 y, yz
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