Suggest plausible mechanisms for the following two reactions given the overall reaction rate law. a. I- + OCI" → Cl- + OI-; -d[I]¯/dr = k[I¯][OCI¯V[OH¯]

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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1. Houston book, pp. 90, 2.35.
Suggest plausible mechanisms for the following two reactions given the
overall reaction rate law.
a. I- + OCI" CI- + OI-; -d[I]/dr = k[I][OCI"V[OH]
%3D
b. C(CH,),CI + OH- → C(CH,),OH + CI; -d[C(CH,),CIJ/dr
k[C(CH,),CI][OHV{[CI] + K'[OH-]}
Transcribed Image Text:1. Houston book, pp. 90, 2.35. Suggest plausible mechanisms for the following two reactions given the overall reaction rate law. a. I- + OCI" CI- + OI-; -d[I]/dr = k[I][OCI"V[OH] %3D b. C(CH,),CI + OH- → C(CH,),OH + CI; -d[C(CH,),CIJ/dr k[C(CH,),CI][OHV{[CI] + K'[OH-]}
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