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Some different views of an octahedral symmetry metal com

Some different views of an octahedral symmetry metal com

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Some different views of an octahedral symmetry metal complex 1 3 1 3 6 3 2 1 4 2 2 View down a C, axis View down a C, axis View down a C, axis On E 8C3 6C2 6C, 3C, i 6S, 8S, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Azg 1 -1 1 -1 z², x² - y? Eg 2 -1 -1 Tig -1 -1 -1 1 -1 T2g (xy, xz, yz) 1 -1 -1 -1 -1 A1u -1 -1 -1 -1 1 1 1 -1 A2u 1 1 -1 -1 -1 -1 -1 1 E -1 -2 1 -2 3 -1 1 -1 -3 -1 (x, y, z) 3 Tzu -1 -1 -3 1 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 2. 3. 3. 2. 3. 3. 1. 2.
Transcribed Image Text:Some different views of an octahedral symmetry metal complex 1 3 1 3 6 3 2 1 4 2 2 View down a C, axis View down a C, axis View down a C, axis On E 8C3 6C2 6C, 3C, i 6S, 8S, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Azg 1 -1 1 -1 z², x² - y? Eg 2 -1 -1 Tig -1 -1 -1 1 -1 T2g (xy, xz, yz) 1 -1 -1 -1 -1 A1u -1 -1 -1 -1 1 1 1 -1 A2u 1 1 -1 -1 -1 -1 -1 1 E -1 -2 1 -2 3 -1 1 -1 -3 -1 (x, y, z) 3 Tzu -1 -1 -3 1 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 2. 3. 3. 2. 3. 3. 1. 2.
Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) V[Choos Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) %3D [ Choose ] >
Transcribed Image Text:Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) V[Choos Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) %3D [ Choose ] >
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