So if 2n^2 could predict the maximum number of electrons in the n shell. Then the 3rd shell should hold 18 electrons since chlorine has 17 electrons in a neutral state how come we say it pursues the octet rule despite it being able to hold 18 electrons? For example, it's shown during an ionic transfer with Na to gain an electron and be satisfied occurring to the octet rule.  Please explain does it have to deal with the orbitals?

Living By Chemistry: First Edition Textbook
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ChapterU2: Smells: Molecular Structure And Properties
SectionU2.17: Thinking (electro) Negatively: Electronegativity Scale
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So if 2n^2 could predict the maximum number of electrons in the n shell. Then the 3rd shell should hold 18 electrons since chlorine has 17 electrons in a neutral state how come we say it pursues the octet rule despite it being able to hold 18 electrons? For example, it's shown during an ionic transfer with Na to gain an electron and be satisfied occurring to the octet rule. 

Please explain does it have to deal with the orbitals?

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