Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Sketch a galvanic cell based on the reaction: Cr3+ (aq) + Cl2 (g) -> Cr2O72- (aq) + Cl- (aq)
Show the direction of electron flow, and identify the cathode and anode. Give the overall balanced equation. Assume that all concentrations are 1.0 M and that all partial pressures are 1.0 atm. Then calculate Eo values for the galvanic cell.
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- Write the half-reactions as they occur at each electrode and the net cell reaction for this electrochemical cell containing indium and cadmium. In(s)||In3+(aq)‖‖Cd2+(aq)||Cd(s)In(s)|In3+(aq)‖Cd2+(aq)|Cd(s) anode: cathode: net cell reaction:arrow_forwardA chemist designs a galvanic cell that uses these two half-reactions: 3+ 2+ Fe (aq)+e → Fe (aq) Cro (aq) + 4H₂O(1)+3e¯ Cr(OH)3(s)+5 OH(aq) Answer the following questions about this cell. Write a balanced equation for the half-reaction that happens at the cathode. Write a balanced equation for the half-reaction that happens at the anode. Write a balanced equation for the overall reaction that powers the cell. Be sure the reaction is half-reaction spontaneous as written. 0 standard reduction potential Ed=+0.771 V 'red E 'red = -0.13 V ロ→ロ × x10 5arrow_forwardWrite the cell notation for an electrochemical cell consisting of an anode where Ni (s) is oxidized to Ni2+ (aq) and a cathode where Cu2+ (aq) is reduced to Cu (s) . Assume all aqueous solutions have a concentration of 1 mol/L.arrow_forward
- A galvanic cell is constructed as follows. One half-cell consists of a platinum wire immersed in a solution containing 1.00 M Sn2+ and 1.00 M Sn4+. The other half-cell has a thallium rod immersed in a solution of 1.00 M Tl+. What is the equilibrium constant at 25° C?(Eo= Tl+ / Tl = −0.34 V.)? What is the cell voltage if the Tl+ concentration is increased 6−fold?arrow_forwardWrite the cell notation for an electrochemical cell consisting of an anode where Cr (s) is oxidized to Cr** (aq) and a cathode where Co2+ (aq) is reduced to Co (s) . Assume all aqueous solutions have a concentration of 1 mol/L.arrow_forwardConsider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of thesearrow_forward
- Write the cell notation for an electrochemical cell consisting of an anode where Mn (s) is oxidized to Mn2+ (ag) and a cathode where Crt (aq) is reduced to Cr (s) . Assume all aqueous solutions have a concentration of 1 mol/L.arrow_forwardA student constructs an electrochemical cell with a half-cell composed of a nickel anode in a 0.10 M Ni2+(aq) solution, and another composed of a silver cathode in a 0.10 M Ag+(aq) solution. The Ecell at 20.0oC is measured as +1.03 V. Calculate the experimental equilibrium constant, K, for the reaction Your answer should have 3 sig figs.arrow_forward
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